Electromagnetic Interference (EMI) Transparent Shielding of Reduced Graphene Oxide (RGO) Interleaved Structure Fabricated by Electrophoretic Deposition

被引:160
作者
Kim, Sanghoon [1 ]
Oh, Joon-Suk [3 ,4 ]
Kim, Myeong-Gi [2 ]
Jang, Woojin [3 ]
Wang, Mei [1 ]
Kim, Youngjun [3 ]
Seo, Hee Won [3 ]
Kim, Ye Chan [1 ]
Lee, Jun-Ho [1 ]
Lee, Youngkwan [5 ]
Nam, Jae-Do [1 ,3 ,4 ]
机构
[1] Sungkyunkwan Univ, Dept Energy Sci, Suwon 440746, Gyeonggi Do, South Korea
[2] Samsung Electromech, LCR Prod Dev Grp, Suwon 443743, Gyeonggi Do, South Korea
[3] Sungkyunkwan Univ, Dept Polymer Sci & Engn, Suwon 440746, Gyeonggi Do, South Korea
[4] Sungkyunkwan Univ, SKKU Adv Inst Nanotechnol SAINT, Suwon 440746, Gyeonggi Do, South Korea
[5] Sungkyunkwan Univ, Dept Chem Engn, Suwon 440746, Gyeonggi Do, South Korea
关键词
RGO; EPD; transparent; flexible; conductive; EMI; SE; FILMS; LAYER;
D O I
10.1021/am503893v
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Here we introduce the electromagnetic shielding effectiveness (SE) of reduced graphene oxide (RGO) sheets interleaved between polyetherimide (PEI) films fabricated by electrophoretic deposition (EPD). Incorporating only 0.66 vol % of RGO, the developed PEI/RGO composite films exhibited an electromagnetic interference shielding effectiveness (EMI SE) at 6.37 dB corresponding to similar to 50% shielding of incident waves. Excellent flexibility and optical transparency up to 62% of visible light was demonstrated. It was achieved by placing the RGO sheets in the localized area as a thin film (ca. 20 nm in thickness) between the PEI films (ca. 2 mu m) to be an interleaved and alternating structure. This unique interleaved structure without any delamination areas was fabricated by a successive application of cathodic and anodic EPD of both RGO and PEI layers. The EPD fabrication process was ensured by an alternating deposition of the quarternized-PEI drops and RGO, each taking positive and negative charges, respectively, in the water medium. We believe that the developed facile fabrication method of RGO interleaved structure with such low volume fraction has great potential to be used as a transparent EMI shielding material.
引用
收藏
页码:17647 / 17653
页数:7
相关论文
共 37 条
[1]   Thin Film Fabrication and Simultaneous Anodic Reduction of Deposited Graphene Oxide Platelets by Electrophoretic Deposition [J].
An, Sung Jin ;
Zhu, Yanwu ;
Lee, Sun Hwa ;
Stoller, Meryl D. ;
Emilsson, Tryggvi ;
Park, Sungjin ;
Velamakanni, Aruna ;
An, Jinho ;
Ruoff, Rodney S. .
JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2010, 1 (08) :1259-1263
[2]  
[Anonymous], [No title captured]
[3]  
Bae S, 2010, NAT NANOTECHNOL, V5, P574, DOI [10.1038/nnano.2010.132, 10.1038/NNANO.2010.132]
[4]   A review on fundamentals and applications of electrophoretic deposition (EPD) [J].
Besra, Laxmidhar ;
Liu, Meilin .
PROGRESS IN MATERIALS SCIENCE, 2007, 52 (01) :1-61
[5]   Electrophoretic deposition of graphene nanosheets on nickel foams for electrochemical capacitors [J].
Chen, Yao ;
Zhang, Xiong ;
Yu, Peng ;
Ma, Yanwei .
JOURNAL OF POWER SOURCES, 2010, 195 (09) :3031-3035
[6]   Characteristics of the electromagnetic interference shielding effectiveness of Al-doped ZnO thin films deposited by atomic layer deposition [J].
Choi, Yong-June ;
Gong, Su Cheol ;
Johnson, David C. ;
Golledge, Stephen ;
Yeom, Geun Young ;
Park, Hyung-Ho .
APPLIED SURFACE SCIENCE, 2013, 269 :92-97
[7]   Electromagnetic interference shielding effectiveness of carbon materials [J].
Chung, DDL .
CARBON, 2001, 39 (02) :279-285
[8]   Solution-Processed Graphite Membrane from Reassembled Graphene Oxide [J].
Ghosh, Titisa ;
Biswas, Chandan ;
Oh, Joonsuk ;
Arabale, Girish ;
Hwang, Taeseon ;
Nguyen Dang Luong ;
Jin, Meihua ;
Lee, Young Hee ;
Nam, Jae-Do .
CHEMISTRY OF MATERIALS, 2012, 24 (03) :594-599
[9]  
Hong S.K., 2012, Nanotechnology, V23, P5
[10]   Flexible Transparent PES/Silver Nanowires/PET Sandwich-Structured Film for High-Efficiency Electromagnetic Interference Shielding [J].
Hu, Mingjun ;
Gao, Jiefeng ;
Dong, Yucheng ;
Li, Kai ;
Shan, Guangcun ;
Yang, Shiliu ;
Li, Robert Kwok-Yiu .
LANGMUIR, 2012, 28 (18) :7101-7106