Diastereoselective Pt Catalyzed Cycloisomerization of Polyenes to Polycycles

被引：33

作者：

Geier, Michael J. ^{[1
]}

Gagne, Michel R. ^{[1
]}

机构：

[1] Univ N Carolina, Dept Chem, Caudill Labs, Chapel Hill, NC 27599 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2014年 / 136卷 / 08期

基金：

加拿大自然科学与工程研究理事会;

关键词：

CATION-OLEFIN REACTIONS; UNACTIVATED ALKENES; POLYCYCLIZATION REACTIONS; ENZYME MECHANISMS; ARYL POLYENES; CYCLIZATION; TURNOVER; CASCADE; 1,6,10-TRIENES; HYDROAMINATION;

D O I：

10.1021/ja500656k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Application of a tridentate NHC containing pincer ligand to Pt catalyzed cascade cyclization reactions has allowed for the catalytic, diastereoselective cycloisomerization of biogenic alkene terminated substrates to the their polycyclic counterparts.

引用

页码：3032 / 3035

页数：4

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