Triethylammonium Halochromates, (C2H5)3NH+[CrO3X]- (X=F ,Cl), Reagents for Efficient Oxidation Coupling of Thiols to Disulfides

被引：0

作者：

Mohammadi, Mohammad Kazem ^{[1
,3
]}

Ghammamy, Shahriare ^{[2
]}

Farjam, Mohammad Hossein

机构：

[1] Islamic Azad Univ, Fac Sci, Ahwaz Branch, Tehran, Iran

[2] Imam Khomeini Int Univ, Fac Sci, Dept Chem, Qazvin 288, Iran

[3] Islamic Azad Univ, Fac Sci, Firoozabad Branch, Tehran, Iran

来源：

CHEMISTRY AND CHEMICAL PROCESS | 2011年

关键词：

Thiol; Oxidation; Disulfide; Triethylammonium Fluorochromate; Triethylammonium Chlorochromate; Solution; Microwave; CONVERSION; BROMINE; SYSTEM;

D O I：

暂无

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

Triethylammonium fluorochromate (TriEAFC) and Triethylammonium chlorochromate (TriEACC) are new efficient reagents, which are prepared easily and oxidized thiols to the corresponding disulfides swiftly. The reactions perform cleanly and terminate simultaneously at the disulfide stage without any side products. Oxidizing of some thiols to their corresponding disulfides was studied in solution at room temperature and under microwave radiation. The easy procedure, simple work-up, short reaction times, and excellent yields are advantages of these reagents.

引用

页码：215 / 219

页数：5

共 9 条

[1] Oxidation of organic substrates using two triethylammonium halochromates(VI), (C2H5)3NH[CrO3X], (X=F, Cl) supported on silica gel
Ghammamy, Shahriare
Dastpeyman, Samaneh
JOURNAL OF THE CHINESE CHEMICAL SOCIETY, 2008, 55 (01) : 229 - 232
[2] Oxidation of organic substrates by trimethylammonium halochromates(VI), (CH3)3NH[CrO3X], (X = F, Cl) on silica gel
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ASIAN JOURNAL OF CHEMISTRY, 2008, 20 (04) : 2797 - 2801
[3] Synthesis and characterization of two new triphenylphosphonium halochromates, (C6H5)3PH[CrO3X], (X = F, Br)
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Mehrani, Kheyrollah
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ARKIVOC, 2007, : 61 - 65
[4] Methyltriphenylphosphonium Halochromates, [Me(Ph)(3)P][CrO3X] (MTriPPXC) (X= F, Cl, Br): the Three New, Mild and Stable Oxidants for Organic Substrates
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Mehrani, Kheyrollah
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[5] Dabco Ammonium Halochromates, C6H14N2comma+ Cr2F2O6comma-(DAXC, X = F, Cl), Reagents for Efficient and Mild Oxidation of Organic Substrates
Mohammadi, M. K.
IRANIAN JOURNAL OF SCIENCE AND TECHNOLOGY TRANSACTION A-SCIENCE, 2018, 42 (A3): : 1185 - 1189
[6] Oxidation of Some Organic Diols with Trialkylammonium Fluorochromates(VI), R3NH[CrO3F], (R= CH3, C2H5, C3H7 and C4H9) at Room Temperature and Under Microwave Condition
Ghammamy, Shahriar
Khorsandtabar, Samira
Moghimi, Ali
Sahebalzamani, Hajar
JOURNAL OF THE MEXICAN CHEMICAL SOCIETY, 2009, 53 (02) : 41 - 43
[7] A comparative study of the ruthenium(VI)dioxocarboxylato salts, [PPh4][RuO2(OCOR)Cl2] (R = CH3, CF3, C6H5, C6F5, C5H11), in the oxidation of alcohols
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[8] Dabco Ammonium Halochromates, C6H14N2+\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$ {\text{C}}_{6} {\text{H}}_{14} {\text{N}}_{2}\,^{ + } $$\end{document}Cr2F2O6-\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$ {\text{Cr}}_{2} {\text{F}}_{2} {\text{O}}_{6}\,^{ - } $$\end{document} (DAXC, X = F, Cl), Reagents for Efficient and Mild Oxidation of Organic Substrates
M. K. Mohammadi
Iranian Journal of Science and Technology, Transactions A: Science, 2018, 42 (3): : 1185 - 1189
[9] OXIDATION REACTIONS USING WATER, HYDROGEN-PEROXIDE AND HALOGENS TO GIVE PALLAD(IV)CYCLOPENTANE COMPLEXES PDX(C4H8)((PZ)(3)BH) (X=OH, CL, BR, I) - THE CRYSTAL-STRUCTURE OF THE HYDROXOPLATINUM(IV) COMPLEX PT(OH) ME(2)((PZ)(3)BH), FORMED BY USE OF WATER AS AN OXIDANT
CANTY, AJ
FRITSCHE, SD
JIN, H
SKELTON, BW
WHITE, AH
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1995, 490 (1-2) : C18 - C19

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