Carbon-Carbon and Carbon-Heteroatom Bond-Forming Transformations Catalyzed by Calcium(II) Triflimide

被引：34
|
作者：
Leboeuf, David [1 ]
Gandon, Vincent [1 ]
机构：
[1] Univ Paris Saclay, Univ Paris Sud, CNRS UMR 8182, Inst Chim Mol & Mat Orsay, Batiment 420, F-91405 Orsay, France
来源：
SYNTHESIS-STUTTGART | 2017年 / 49卷 / 07期
关键词：
ammonium salt; calcium; C-C bond-forming reactions; C-O bond functionalization; C-X bond-forming reactions; homogeneous catalysis; weakly coordinating anion; DONOR-ACCEPTOR CYCLOPROPANES; RING-OPENING CYCLIZATIONS; NAZAROV CYCLIZATION; HYDROGEN-PEROXIDE; OLEFIN EPOXIDATION; ROOM-TEMPERATURE; ALCOHOLS; ALKENES; BISMUTH; CYCLOISOMERIZATION;
D O I：
10.1055/s-0036-1588406
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The aim of this short review is to highlight the interest of using Ca(NTf2)(2) as catalyst in C-C and C-X bond-forming reactions. The ability of this complex to activate alcohols, alkenes, ketones, and cyclopropanes towards nucleophilic additions and other chemical processes is shown though a set of selected examples, which illustrate the substrate scope and the synthetic applications offered by this green' calcium salt. 1 Introduction 2 Synthetic Applications 3 Conclusion
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页码：1500 / 1508
页数：9
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