In situ growth of ultrashort rice-like CuO nanorods supported on reduced graphene oxide nanosheets and their lithium storage performance

被引：8
作者：
Li, Gangyong [1 ]
He, Binhong [1 ]
Zhou, Minjie [1 ]
Wang, Guoxiang [1 ]
Zhou, Ningbo [1 ]
Xu, Wenyuan [1 ]
Jing, Mingjun [1 ]
Hou, Zhaohui [1 ]
机构：
[1] Hunan Inst Sci & Technol, Sch Chem & Chem Engn, Yueyang 414006, Peoples R China
来源：
IONICS | 2017年 / 23卷 / 03期
基金：
中国国家自然科学基金;
关键词：
CuO nanorods; Rice-like; Reduced graphene oxide; Lithium-ion batteries; BINDER-FREE ANODE; FACILE SYNTHESIS; REVERSIBLE CAPACITY; ELECTRODE MATERIALS; NEGATIVE-ELECTRODE; CARBON; NANOPARTICLES; FABRICATION; COMPOSITE; ARRAYS;
D O I：
10.1007/s11581-016-1822-y
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A facile refluxing strategy in aqueous solution was engaged to synthesize ultrashort rice-like CuO nanorods/reduced graphene oxide (CuO-NRs/rGO) composite. The result of the high-resolution transmission electron microscopy shows that the as-synthesized rice-like CuO nanorods have a uniform size of about 8 nm in width and 28 nm in length and are homogenously dispersed on rGO nanosheets. The CuO nanorods are uniformly dispersed and immobilized by the graphene nanosheets reduced from GO. The resultant CuO-NRs/rGO composite as anode material for lithium-ion batteries displays better electrochemical properties than those of pure CuO-NRs and rGO nanosheets. The high reversible capacity and good stability can be ascribed to the presence of rGO nanosheets.
引用
收藏
页码：607 / 616
页数：10
相关论文
共 48 条
[1]   A large-scale, green route to synthesize of leaf-like mesoporous CuO as high-performance anode materials for lithium ion batteries [J].
Bai, Zhongchao ;
Zhang, Yuwen ;
Zhang, Yaohui ;
Guo, Chunli ;
Tang, Bin .
ELECTROCHIMICA ACTA, 2015, 159 :29-34
[2]   Electrochemical performance of polycrystalline CuO nanowires as anode material for Li ion batteries [J].
Chen, L. B. ;
Lu, N. ;
Xu, C. M. ;
Yu, H. C. ;
Wang, T. H. .
ELECTROCHIMICA ACTA, 2009, 54 (17) :4198-4201
[3]   Multi-yolk-shell copper oxide@carbon octahedra as high-stability anodes for lithium-ion batteries [J].
Chen, Tao ;
Hu, Yi ;
Cheng, Baorui ;
Chen, Renpeng ;
Lv, Hongling ;
Ma, Lianbo ;
Zhu, Guoyin ;
Wang, Yanrong ;
Yan, Changzeng ;
Tie, Zuoxiu ;
Jin, Zhong ;
Liu, Jie .
NANO ENERGY, 2016, 20 :305-314
[4]   Facile fabrication of CuO 1D pine-needle-like arrays for super-rate lithium storage [J].
Chen, Xin ;
Zhang, Naiqing ;
Sun, Kening .
JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (30) :15080-15084
[5]   Comparing Leaching of Different Copper Oxide Nanoparticles and Ammoniacal Copper Salt from Wood [J].
Ding, Xiaochu ;
Meneses, Martha Barajas ;
Albukhari, Soha M. ;
Richter, Dana L. ;
Matuana, Laurent M. ;
Heiden, Patricia A. .
MACROMOLECULAR MATERIALS AND ENGINEERING, 2013, 298 (12) :1335-1343
[6]   Preparation and characterization of CoO used as anodic material of lithium battery [J].
Do, JS ;
Weng, CH .
JOURNAL OF POWER SOURCES, 2005, 146 (1-2) :482-486
[7]   Ultrathin NiO nanosheets anchored on a highly ordered nanostructured carbon as an enhanced anode material for lithium ion batteries [J].
Fan, Zhaoyang ;
Liang, Jin ;
Yu, Wei ;
Ding, Shujiang ;
Cheng, Shaodong ;
Yang, Guang ;
Wang, Yonglong ;
Xi, Yingxin ;
Xi, Kai ;
Kumar, R. Vasant .
NANO ENERGY, 2015, 16 :152-162
[8]   Raman spectrum of graphene and graphene layers [J].
Ferrari, A. C. ;
Meyer, J. C. ;
Scardaci, V. ;
Casiraghi, C. ;
Lazzeri, M. ;
Mauri, F. ;
Piscanec, S. ;
Jiang, D. ;
Novoselov, K. S. ;
Roth, S. ;
Geim, A. K. .
PHYSICAL REVIEW LETTERS, 2006, 97 (18)
[9]   Pore size determination in modified micro- and mesoporous materials.: Pitfalls and limitations in gas adsorption data analysis [J].
Groen, JC ;
Peffer, LAA ;
Pérez-Ramírez, J .
MICROPOROUS AND MESOPOROUS MATERIALS, 2003, 60 (1-3) :1-17
[10]   Facile synthesis and lithium storage performance of hollow CuO microspheres [J].
He, Simin ;
Li, Jinshan ;
Wang, Jun ;
Yang, Guangcheng ;
Qiao, Zhiqiang .
MATERIALS LETTERS, 2014, 129 :5-7
12345