Lanthanide crown ether complexes of p-sulfonatocalix[5]arene

被引:31
|
作者
Dalgarno, SJ
Hardie, MJ
Warren, JE
Raston, CL [1 ]
机构
[1] Univ Western Australia, Sch Biomed & Chem Sci, Perth, WA 6909, Australia
[2] Univ Leeds, Dept Chem, Leeds LS2 9JT, W Yorkshire, England
[3] CCLRC, Daresbury Lab, Warrington WA4 4AD, Cheshire, England
关键词
D O I
10.1039/b407207c
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Two types of arrays are formed in water involving aza-crown ethers, p-sulfonatocalix[5] arene and europium(III) ions. One is a co-ordination polymer connecting calixarenes, sodium ions and lanthanide ions based on 'ferris wheel' moieties incorporating aza-18-crown-6 and sodium ions. The second structure is a host-guest arrangement with di-protonated diaza-18-crown-6 in the cavity of the calixarenes as part of secondary coordination spheres of aquated europium(III) ions.
引用
收藏
页码:2413 / 2416
页数:4
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