Influence of Heat Curing on Structure and Physicochemical Properties of Phenolic Acid Loaded Proteinaceous Electrospun Fibers

被引:20
作者
Neo, Yun Ping [1 ]
Perera, Conrad O. [1 ]
Nieuwoudt, Michel K. [1 ]
Zujovic, Zoran [1 ]
Jin, Jianyong [1 ]
Ray, Sudip [1 ]
Gizdavic-Nikolaidis, Marija [1 ]
机构
[1] Univ Auckland, Sch Chem Sci, Auckland 1, New Zealand
关键词
electrospinning; zein; gallic acid; heat treatment; physicochemical properties; SOLID-STATE; ZEIN; CONFORMATION; FABRICATION; KERATIN; FILMS;
D O I
10.1021/jf500841m
中图分类号
S [农业科学];
学科分类号
09 ;
摘要
Effects of heat treatment on structure and physicochemical properties of zein (Ze) and gallic acid loaded zein (Ze-GA) electrospun fiber mats were investigated. The electrospun fiber mats displayed different surface and physicochemical properties after being heat-cured at 150 degrees C for 24 h, which were closely related to the initial amount of loaded gallic acid. The gallic acid was released from the Ze-GA fiber mats in a constant manner, but heat curing decreased the rate of release. Heat curing remarkably increased the molecular weight of the Ze and Ze-GA electrospun fiber mats. Attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR) analysis of the fiber mats indicated variations in zein protein secondary structure after heat curing. C-13 solid state NMR (SS-NMR) confirmed the presence of a different chemical environment among the fiber mats. The fabrication of heat-cured zein based electrospun fibers in this study may find applications in the food packaging industry.
引用
收藏
页码:5163 / 5172
页数:10
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