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Influence of Heat Curing on Structure and Physicochemical Properties of Phenolic Acid Loaded Proteinaceous Electrospun Fibers
被引:20
作者:
Neo, Yun Ping
[1
]
Perera, Conrad O.
[1
]
Nieuwoudt, Michel K.
[1
]
Zujovic, Zoran
[1
]
Jin, Jianyong
[1
]
Ray, Sudip
[1
]
Gizdavic-Nikolaidis, Marija
[1
]
机构:
[1] Univ Auckland, Sch Chem Sci, Auckland 1, New Zealand
关键词:
electrospinning;
zein;
gallic acid;
heat treatment;
physicochemical properties;
SOLID-STATE;
ZEIN;
CONFORMATION;
FABRICATION;
KERATIN;
FILMS;
D O I:
10.1021/jf500841m
中图分类号:
S [农业科学];
学科分类号:
09 ;
摘要:
Effects of heat treatment on structure and physicochemical properties of zein (Ze) and gallic acid loaded zein (Ze-GA) electrospun fiber mats were investigated. The electrospun fiber mats displayed different surface and physicochemical properties after being heat-cured at 150 degrees C for 24 h, which were closely related to the initial amount of loaded gallic acid. The gallic acid was released from the Ze-GA fiber mats in a constant manner, but heat curing decreased the rate of release. Heat curing remarkably increased the molecular weight of the Ze and Ze-GA electrospun fiber mats. Attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR) analysis of the fiber mats indicated variations in zein protein secondary structure after heat curing. C-13 solid state NMR (SS-NMR) confirmed the presence of a different chemical environment among the fiber mats. The fabrication of heat-cured zein based electrospun fibers in this study may find applications in the food packaging industry.
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页码:5163 / 5172
页数:10
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