Novel immobilization method of enzymes using a hydrophilic polymer support

被引：32

作者：

Kobayashi, Juta ^{[1
]}

Mori, Yuichiro ^{[1
]}

Kobayashi, Shu ^{[1
]}

机构：

[1] Univ Tokyo, HFRE Div, ERATO, Japan Sci & Technol Agcy,Grad Sch Pharmaceut Sci,, Tokyo 1130033, Japan

来源：

CHEMICAL COMMUNICATIONS | 2006年 / 40期

关键词：

RUTHENIUM CATALYSTS; LIPASE; OXIDATION; MEMBRANE; ALCOHOLS;

D O I：

10.1039/b609335c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel immobilization of an enzyme with a hydrophilic polymer support in organic solvents has been developed utilizing the "polymer-incarcerated (PI) method", which has been used to immobilize metal catalysts; the kinetic resolution of secondary alcohols was found to proceed more smoothly using immobilized lipases (CALB) than free lipases.

引用

页码：4227 / 4229

页数：3

共 31 条

[1] The polymer incarcerated method for the preparation of highly active heterogeneous palladium catalysts [J].

Akiyama, R ;

Kobayashi, S .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (12) :3412-3413

[2] Immobilization of lipase using hydrophilic polymers in the form of hydrogel beads [J].

Betigeri, SS ;

Neau, SH .

BIOMATERIALS, 2002, 23 (17) :3627-3636

[3] Enzyme encapsulation in layer-by-layer engineered polymer multilayer capsules [J].

Caruso, F ;

Trau, D ;

Möhwald, H ;

Renneberg, R .

LANGMUIR, 2000, 16 (04) :1485-1488

[4] A rapid and easy procedure of biosensor fabrication by microencapsulation of enzyme in hydrophilic synthetic latex films. Application to the amperometric determination of glucose [J].

Cosnier, S ;

Szunerits, S ;

Marks, RS ;

Novoa, A ;

Puech, L ;

Perez, E ;

Rico-Lattes, I .

ELECTROCHEMISTRY COMMUNICATIONS, 2000, 2 (12) :851-855

[5] Rice straw as a support for immobilization of microbial lipase [J].

de Castro, HF ;

de Lima, R ;

Roberto, IC .

BIOTECHNOLOGY PROGRESS, 2001, 17 (06) :1061-1064

[6]

DEVOS DE, 2000, CHIRAL CATALYST IMMO, V5, P97

[7] Preparation and properties of lipase immobilized on MCM-36 support [J].

Dumitriu, E ;

Secundo, F ;

Patarin, J ;

Fechete, L .

JOURNAL OF MOLECULAR CATALYSIS B-ENZYMATIC, 2003, 22 (3-4) :119-133

[8] Enantioselective enzymatic desymmetrizations in organic synthesis [J].

García-Urdiales, E ;

Alfonso, I ;

Gotor, V .

CHEMICAL REVIEWS, 2005, 105 (01) :313-354

[9] Immobilization of lipase on chitin and its use in nonconventional blocatalysis [J].

Gomes, FM ;

Pereira, EB ;

de Castro, HF .

BIOMACROMOLECULES, 2004, 5 (01) :17-23

[10]

GRAY CJ, 1990, ENZYME MICROB TECH, V12, P800, DOI 10.1016/0141-0229(90)90155-J

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