Alkyl polyglycoside surfactant-alcohol cosolvent formulations for improved oil recovery

被引:135
作者
Iglauer, Stefan [1 ]
Wu, Yongfu [1 ]
Shuler, Patrick [1 ]
Tang, Yongchun [1 ]
Goddard, William A., III [2 ]
机构
[1] CALTECH, Div Chem & Chem Engn, PEER Ctr, Covina, CA 91722 USA
[2] CALTECH, Div Chem & Chem Engn, Mat & Proc Simulat Ctr MSC, Pasadena, CA 91106 USA
关键词
Alkyl polyglycoside; Alcohol cosolvents; Ultra-low interfacial tension; Enhanced oil recovery; MICROEMULSIONS; TENSIONS;
D O I
10.1016/j.colsurfa.2009.01.015
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We examine here the suitability of alkyl polyglycosides (APG) for improved oil recovery (IOR) applications. In recent years, these nonionic carbohydrate-based surfactants have become a significant commercial product (80,000 tons/year) with widespread use in household and agricultural products. Our laboratory study determined several characteristics of common APG surfactant formulations, in particular their capability to create low interfacial tensions (IFT) with n-alkane hydrocarbons. Our formulations included a wide range of alcohol cosurfactants with APG surfactants. We found APG-cosurfactant combinations that exhibit low IFT values of 0.01 mN/m or less versus n-octane. Our laboratory tests confirmed these APG formulations can provide useful IFT properties that are largely independent of both salinity and temperature. We report a coreflood test conducted on a Berea sandstone core using a selected formulation that exhibits oil recovery as high as 85% IOIP (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:48 / 59
页数:12
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