Alkyl polyglycoside surfactant-alcohol cosolvent formulations for improved oil recovery

被引:135
作者
Iglauer, Stefan [1 ]
Wu, Yongfu [1 ]
Shuler, Patrick [1 ]
Tang, Yongchun [1 ]
Goddard, William A., III [2 ]
机构
[1] CALTECH, Div Chem & Chem Engn, PEER Ctr, Covina, CA 91722 USA
[2] CALTECH, Div Chem & Chem Engn, Mat & Proc Simulat Ctr MSC, Pasadena, CA 91106 USA
关键词
Alkyl polyglycoside; Alcohol cosolvents; Ultra-low interfacial tension; Enhanced oil recovery; MICROEMULSIONS; TENSIONS;
D O I
10.1016/j.colsurfa.2009.01.015
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We examine here the suitability of alkyl polyglycosides (APG) for improved oil recovery (IOR) applications. In recent years, these nonionic carbohydrate-based surfactants have become a significant commercial product (80,000 tons/year) with widespread use in household and agricultural products. Our laboratory study determined several characteristics of common APG surfactant formulations, in particular their capability to create low interfacial tensions (IFT) with n-alkane hydrocarbons. Our formulations included a wide range of alcohol cosurfactants with APG surfactants. We found APG-cosurfactant combinations that exhibit low IFT values of 0.01 mN/m or less versus n-octane. Our laboratory tests confirmed these APG formulations can provide useful IFT properties that are largely independent of both salinity and temperature. We report a coreflood test conducted on a Berea sandstone core using a selected formulation that exhibits oil recovery as high as 85% IOIP (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:48 / 59
页数:12
相关论文
共 37 条
[1]   INFLUENCE OF FLUID VISCOSITY, INTERFACIAL-TENSION, AND FLOW VELOCITY ON RESIDUAL OIL SATURATION LEFT BY WATERFLOOD [J].
ABRAMS, A .
SOCIETY OF PETROLEUM ENGINEERS JOURNAL, 1975, 15 (05) :437-447
[2]  
Balzer D., 2000, SURFACTANT SCI SERIE, V91
[3]  
BALZER D, 1991, Patent No. 19914985
[4]  
Balzer D., 1991, TENSIDE SURFACT DET, V28, P419, DOI [10.1515/tsd-1991-280610, DOI 10.1515/TSD-1991-280610]
[5]  
BERTSCH H, 1934, Patent No. 2049758
[6]  
Bourrel M., 1988, MICROEMULSIONS RELAT
[7]  
CAYAIS JL, 1977, J COLLOID INTERF SCI, V59, P31
[8]  
CAYAIS JL, 1977, MEASUREMENT LOW INTE
[9]  
*COGN CORP, 2004, TECHN DAT SHEET
[10]   MICRO-EMULSIONS AND THE FLEXIBILITY OF OIL-WATER INTERFACES [J].
DEGENNES, PG ;
TAUPIN, C .
JOURNAL OF PHYSICAL CHEMISTRY, 1982, 86 (13) :2294-2304