Synthesis of C-C-bridged bis-isoflavones

被引：23

作者：

Al-Maharik, N

Kaltia, SAA

Mutikainen, I

Wähälä, K

机构：

[1] Univ Helsinki, Organ Chem Lab, FIN-00014 Helsinki, Finland

[2] Univ Helsinki, Inorgan Chem Lab, Dept Chem, FIN-00014 Helsinki, Finland

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2000年 / 65卷 / 08期

关键词：

D O I：

10.1021/jo991404g

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Unique C-C-bridged bis-isoflavones 5, 8, and 9 were obtained by reaction of 2-bromomethyl-7,4'-dimethoxyisoflavone 4 with ethyl cyanoacetate anion or tetraethylammonium cyanide or by Pd-catalyzed ethoxycarbonylation, respectively. The phenolic carboxylic acid 7 is available from 5 in two steps.

引用

页码：2305 / 2308

页数：4

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