Raman and infrared study of the crystals with molecular anions in the region of a solid-liquid phase transition

被引：29

作者：

Gafurov, MM ^{[1
]}

Aliev, AR ^{[1
]}

Akhmedov, IR ^{[1
]}

机构：

[1] Russian Acad Sci, Daghestan Sci Ctr, Inst Phys, Makhachkala 367003, Russia

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 2002年 / 58卷 / 12期

基金：

俄罗斯基础研究基金会;

关键词：

vibrational spectroscopy; Raman scattering; infrared absorption; molten salt; ionic crystal; solid-liquid phase transition; pre-melting behavior; molecular relaxation; rotational motion; vibrational dephasing;

D O I：

10.1016/S1386-1425(02)00014-8

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

It is presented the Raman and infrared (IR) spectroscopic investigations of the thiocyanates: LiSCN, NaSCN, KSCN, RbSCN, CsSCN; nitrates: Ca(NO3)(2), Sr(NO3)(2), Ba(NO3)(2), Pb(NO3)(2); and perrhenates: LiReO4, NaReO4, KReO4 in the region of a solid-liquid phase transition. The differences in a pre-melting behavior of this salts were found which can be attributed to a different geometry of the SCN-, NO3- and ReO4- anions. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：2683 / 2692

页数：10

共 48 条

[1]

ALIEV AR, 1992, RASPLAVY, V1, P30

[2]

ALIEV AR, 1998, ZH PRIKL SPEKTROSK, V65, P931

[3]

ALIEV AR, 1995, ZH PRIKL SPEKTROSK, V62, P151

[4]

ALIEV AR, 2001, ZH FIZ KHIM, V75, P477

[5]

ALIEV AR, 1993, ZH PRIKL SPEKTROSK, V59, P465

[6] IONIC-CONDUCTIVITY IN SINGLE-CRYSTALS OF BARIUM NITRATE [J].

BABU, KS ;

CHIRANJIVI, T .

JOURNAL OF PHYSICS C-SOLID STATE PHYSICS, 1980, 13 (23) :L587-L589

[7] ELECTRICAL TRANSPORT IN SINGLE-CRYSTALS OF FLUORITE TYPE ALKALINE-EARTH NITRATES - SR(NO3)2,SR(NO3)2-NA,SR(NO3)2-AL AND BA(NO3)2-K [J].

BABU, KS ;

CHIRANJIVI, T .

SOLID STATE IONICS, 1984, 13 (01) :7-14

[8] IONIC INTERACTIONS IN CRYSTALS - INFRARED AND RAMAN SPECTRA OF POWDERED CA(NO3)2, SR(NO3)2, BA(NO3)2, AND PB(NO3)2 [J].

BROOKER, MH ;

IRISH, DE ;

BOYD, GE .

JOURNAL OF CHEMICAL PHYSICS, 1970, 53 (03) :1083-&

[9] STRUCTURE OF AQUEOUS PERTECHNETATE ION BY RAMAN + INFRARED SPECTROSCOPY . RAMAN + INFRARED SPECTRA OF CRYSTALLINE KTCO4,KREO4,NA2MOO4,NA2WO4,NA2MOO4.2H2O,NA2WO4.2H2O [J].

BUSEY, RH ;

KELLER, OL .

JOURNAL OF CHEMICAL PHYSICS, 1964, 41 (01) :215-&

[10] TEMPERATURE-DEPENDENT RAMAN-SPECTRA OF MONOCLINIC AND CUBIC LI2SO4 [J].

CAZZANELLI, E ;

FRECH, R .

JOURNAL OF CHEMICAL PHYSICS, 1984, 81 (11) :4729-4736

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