Excess enthalpies of (di-n-butyl ether+2,2,4-trimethylpentane plus heptane, or octane) at the temperature 298.15 K

被引:9
作者
Peng, DY [1 ]
Benson, GC [1 ]
Lu, BCY [1 ]
机构
[1] Univ Ottawa, Dept Chem Engn, Ottawa, ON K1N 6N5, Canada
基金
加拿大自然科学与工程研究理事会;
关键词
excess enthalpy; ternary mixture; di-n-butyl ether; 2,2,4-trimethylpentane; n-alkanes; Liebermann-Fried model;
D O I
10.1006/jcht.2000.0822
中图分类号
O414.1 [热力学];
学科分类号
摘要
Measurements of excess molar enthalpies at the temperature 298.15 K in a flow microcalorimeter, are reported for the ternary mixtures [x(l){CH3(CH2)(3)}(2)O+ x(2)(CH3)(3)CCH2CH(CH3)(2)+(1-x(l)-x(2))CH3(CH2)(v)CH3] where v=5 and 6. Smooth representations of the results are described and used to construct constant-enthalpy contours on Roozeboom diagrams. It is shown that useful estimates of the ternary enthalpies can be obtained from the Liebermann-Fried model, using only the physical properties of the components and their binary mixtures. (C) 2002 Elsevier Science Ltd. All fights reserved.
引用
收藏
页码:413 / 422
页数:10
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