Application of Fourier transform infrared spectroscopy in the study of interactions between PVC and plasticizers:: PVC/plasticizer compatibility versus chemical structure of plasticizer

被引:49
作者
Gonzalez, N.
Fernandez-Berridi, M. J. [1 ]
机构
[1] UPV, Fac Quim, Dept Ciencia & Tecnol Polimeros, San Sebastian 20080, Spain
[2] UPV, Fac Quim, Inst Mat Polimer POLYMAT, San Sebastian 20080, Spain
关键词
polyvinylchloride; plasticizers; interactions; compatibility; FTIR spectroscopy;
D O I
10.1002/app.23381
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Fourier transform infrared spectroscopy is applied in the study of interactions between PVC resin and plasticizers in flexible PVC systems. The comparison of the theoretical infrared spectra coming from the addition of the respective component infrared spectra with those of PVC/ plasticizer experimental systems gives information about polymer/plasticizer interaction degree. In addition, solvation capacity of the plasticizer varies as a function of its chemical structure, giving rise to compatibility differences between the system components. (c) 2006 Wiley Periodicals, Inc.
引用
收藏
页码:1731 / 1737
页数:7
相关论文
共 29 条
[1]   POLYMER-DILUENT INTERACTIONS .2. POLYVINYL CHLORIDE-DILUENT INTERACTIONS [J].
ANAGNOSTOPOULOS, CE ;
CORAN, AY .
JOURNAL OF POLYMER SCIENCE, 1962, 57 (165) :1-&
[2]  
ANAGNOSTOPOULOS CE, 1965, MOD PLAST, V43, P141
[3]  
[Anonymous], J APPL POLYM SCI
[4]  
[Anonymous], 1981, TECHNOLOGY PLASTICIZ
[5]   Fourier transform infrared spectroscopy applied to the study of PVC decomposition [J].
Beltran, M ;
Marcilla, A .
EUROPEAN POLYMER JOURNAL, 1997, 33 (07) :1135-1142
[6]  
BELTRAN M, 1997, EUR POLYM J, V22, P453
[7]   THERMODYNAMIC INTERACTIONS IN POLYMER SYSTEMS BY GAS-LIQUID-CHROMATOGRAPHY .4. INTERACTIONS BETWEEN COMPONENTS IN A MIXED STATIONARY PHASE [J].
DESHPAND.DD ;
PATTERSO.D ;
SCHREIBE.HP ;
SU, CS .
MACROMOLECULES, 1974, 7 (04) :530-535
[8]   FTIR OF POLYCAPROLACTONE POLY(VINYLIDENE CHLORIDE-CO-ACRYLONITRILE) MISCIBLE BLENDS [J].
GARTON, A ;
AUBIN, M ;
PRUDHOMME, RE .
JOURNAL OF POLYMER SCIENCE PART C-POLYMER LETTERS, 1983, 21 (01) :45-47
[9]   Tacticity induced molecular microstructure dependence of physical properties of polymers: Fundamentals and overview of some tentative correlations [J].
Guarrotxena, N ;
Tiemblo, P ;
Martinez, G ;
Gomez-Elvira, JM ;
Millan, J .
EUROPEAN POLYMER JOURNAL, 1998, 34 (5-6) :833-839
[10]   Concentration dependency of interaction parameter between PVC and plasticizers using inverse gas chromatography [J].
Huang, JC ;
Deanin, RD .
JOURNAL OF APPLIED POLYMER SCIENCE, 2004, 91 (01) :146-156