Synthesis of polyesters as binders for deinkable inks .3. Structural study by high resolution C-13 and H-1 nmr spectroscopies of the copolyesterification between o-phthalic anhydride, oleic acid and neopentyl glycol in bulk at 205 degrees C

被引：6
作者：
LopezGonzalez, MMC [1 ]
Cudero, MJC [1 ]
BarralesRienda, JM [1 ]
机构：
[1] CSIC,INST CIENCIA & TECNOL POLIMEROS,DEPT QUIM FIS POLIMEROS,E-28006 MADRID,SPAIN
来源：
POLYMER | 1997年 / 38卷 / 25期
关键词：
bulk copolyesterification; o-phthalic anhydride; oleic acid;
D O I：
10.1016/S0032-3861(97)00190-0
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Analysis of the copolyesterification in bulk without any external catalyst at 205 degrees C between o-phthalic anhydride, oleic acid and neopentyl glycol (2,2-dimethyl-1,3-propanediol) with a mole ratio ([-COOH]/[-OH]) = 0.70 has been carried out by high resolution C-13 and H-1 n.m.r. The different polymeric sequences and several monomeric structures formed during the copolyesterification have been identified and quantitatively determined. (C) 1997 Elsevier Science Ltd.
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收藏
页码：6219 / 6233
页数：15
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