Cis/Cis-2,5-Dipropenylthiophene Monomers for High-Molecular-Weight Poly(2,5-thienylene vinylene)s through Acyclic Diene Metathesis Polymerization

被引：14

作者：

Yang, Guoshun ^{[1
]}

Hu, Keda ^{[1
]}

Qin, Yang ^{[1
]}

机构：

[1] Univ New Mexico, Dept Chem & Chem Biol, Albuquerque, NM 87131 USA

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2014年 / 52卷 / 05期

基金：

美国国家科学基金会;

关键词：

acyclic diene metathesis (ADMET); conjugated polymers; metathesis; hydrogenation; kinetics (polym; poly(thienylene vinylene); ACTIVE-MATRIX DISPLAYS; THIN-FILM-TRANSISTOR; ORGANIC SOLAR-CELLS; POLY(THIENYLENE VINYLENE); BAND-GAP; DERIVATIVES; ADMET; POLYMERS; ROUTE; ELECTROLUMINESCENCE;

D O I：

10.1002/pola.27042

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The synthesis of the 2,5-dipropenylthiophene monomer possessing exclusively cis-double bond configurations through the reduction of a dipropynylthiophene precursor is reported. Lindlar's catalyst is found to be completely ineffective, while a dissolving metal method involving activated zinc is successful in alkyne reduction to cis-alkenes with high yields and excellent selectivity. The acyclic diene metathesis polymerization of the monomer affords the poly(2,5-thienylene vinylene) polymer of a high molecular weight. Copyright © 2013 Wiley Periodicals, Inc.

引用

页码：591 / 595

页数：5

共 68 条

[1]

[Anonymous], 2007, HANDBOOK OF CONDUCTI

[2]

[Anonymous], NATO ASI SERIES META

[3] Synthesis of conjugated oligomers and polymers: the organometallic way [J].

Babudri, F ;

Farinola, GM ;

Naso, F .

JOURNAL OF MATERIALS CHEMISTRY, 2004, 14 (01) :11-34

[4] Synthesis of poly(2,5-Thienylene Vinylene) and its derivatives: Low band gap materials for photovoltaics [J].

Banishoeib, F. ;

Henckens, A. ;

Fourier, S. ;

Vanhooyland, G. ;

Breselge, M. ;

Manca, J. ;

Cleij, T. J. ;

Lutsen, L. ;

Vanderzande, D. ;

Nguyen, Le Huong ;

Neugebauer, Helmut ;

Sariciftci, Niyazi Serdar .

THIN SOLID FILMS, 2008, 516 (12) :3978-3988

[5] The synthesis of regio-regular poly(3-alkyl-2,5-thienylene vinylene) derivatives using lithium bis(trimethylsilyl)amide (LHMDS) in the dithiocarbamate precursor [J].

Banishoeib, F. ;

Adriaensens, P. ;

Berson, S. ;

Guillerez, S. ;

Douheret, O. ;

Manca, J. ;

Fourier, S. ;

Cleij, T. J. ;

Lutsen, L. ;

Vanderzande, D. .

SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2007, 91 (11) :1026-1034

[6] STEREOSPECIFIC SYNTHESES AND SPECTROSCOPIC PROPERTIES OF ISOMERIC 2,4,6,8-UNDECATETRAENES - NEW HYDROCARBONS FROM THE MARINE BROWN ALGA-GIFFORDIA-MITCHELLAE .4. [J].

BOLAND, W ;

SIELER, C ;

FEIGEL, M .

HELVETICA CHIMICA ACTA, 1987, 70 (04) :1025-1040

[7] Polymer-Fullerene Bulk-Heterojunction Solar Cells [J].

Brabec, Christoph J. ;

Gowrisanker, Srinivas ;

Halls, Jonathan J. M. ;

Laird, Darin ;

Jia, Shijun ;

Williams, Shawn P. .

ADVANCED MATERIALS, 2010, 22 (34) :3839-3856

[8] Alkene Metathesis - A Tool for the Synthesis of Conjugated Polymers [J].

Bunz, Uwe H. F. ;

Maeker, Dominic ;

Porz, Michael .

MACROMOLECULAR RAPID COMMUNICATIONS, 2012, 33 (10) :886-910

[9] LIGHT-EMITTING-DIODES BASED ON CONJUGATED POLYMERS [J].

BURROUGHES, JH ;

BRADLEY, DDC ;

BROWN, AR ;

MARKS, RN ;

MACKAY, K ;

FRIEND, RH ;

BURN, PL ;

HOLMES, AB .

NATURE, 1990, 347 (6293) :539-541

[10] Stille Polycondensation for Synthesis of Functional Materials [J].

Carsten, Bridget ;

He, Feng ;

Son, Hae Jung ;

Xu, Tao ;

Yu, Luping .

CHEMICAL REVIEWS, 2011, 111 (03) :1493-1528

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