Base-free oxidation of glucose to gluconic acid using supported gold catalysts

被引：51

作者：

Cao, Yueling ^{[1
,2
,3
]}

Liu, Xi ^{[1
]}

Iqbal, Sarwat ^{[1
]}

Miedziak, Peter J. ^{[1
]}

Edwards, Jennifer K. ^{[1
]}

Armstrong, Robert D. ^{[1
]}

Morgan, David J. ^{[1
]}

Wang, Junwei ^{[2
]}

Hutchings, Graham J. ^{[1
]}

机构：

[1] Cardiff Univ, Sch Chem, Cardiff Catalysis Inst, Cardiff CF10 3AT, S Glam, Wales

[2] Chinese Acad Sci, Inst Coal Chem, Taiyuan 030001, Peoples R China

[3] Univ Chinese Acad Sci, Beijing 100049, Peoples R China

来源：

CATALYSIS SCIENCE & TECHNOLOGY | 2016年 / 6卷 / 01期

基金：

英国工程与自然科学研究理事会; 欧洲研究理事会;

关键词：

PROMOTED PALLADIUM CATALYSTS; SELECTIVE OXIDATION; AEROBIC OXIDATION; INCIPIENT WETNESS; HYDROGEN-PEROXIDE; NANOPARTICLES; CONVERSION; STABILITY; PRECURSORS; MECHANISM;

D O I：

10.1039/c5cy00732a

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

1% Au/TiO2 catalysts prepared by a range of preparation methods were studied for the base-free oxidation of glucose. The highest catalytic activity was observed with the catalyst prepared by the sol-immobilization method. Furthermore we have studied the effect of the post-synthesis treatments of treatment with water, or heating in air on the activity. The catalyst calcined at 250 degrees C showed optimal activity and selectivity. Additionally, we studied the effect of the amount of stabilising ligand in the sol-immobilisation method and observed that this is a key parameter with respect to determining the catalyst's activity.

引用

页码：107 / 117

页数：11

共 45 条

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