(C6H17N3)[Zn4(PO4)2(HPO3)2]:: a new layered zinc phosphate-phosphite templated by 1-(2-Aminoethyl) piperazine

被引：13

作者：

Chen, XX ^{[1
]}

Wang, Y ^{[1
]}

Yu, JH ^{[1
]}

Zou, Y ^{[1
]}

Xu, RR ^{[1
]}

机构：

[1] Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130023, Peoples R China

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 2004年 / 177卷 / 07期

基金：

中国国家自然科学基金;

关键词：

layer; zinc phosphate-phosphite; hydrothermal synthesis; structure; host-guest system;

D O I：

10.1016/j.jssc.2004.03.039

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Employing 1-(2-Aminoethyl) piperazine as a template, a new organically templated layered zinc phosphate-phosphite (C6H17N3)[Zn-4(PO4)(2)(HPO3)(2)] has been prepared hydrothermally. Single-crystal X-ray diffraction analysis shows that it crystallizes in the monoclinic space group Cc with a = 5.3272(11) Angstrom, b = 17.146(3) Angstrom, c = 22.071(4) Angstrom, beta = 94.58(3)degrees, V = 2009.5(7) Angstrom(3), Z = 4, R-1 = 0.0201 (I > 2sigma(I)) and wR(2) = 0.0812 (all data). The inorganic network is based on strictly alternating ZnO4 tetrahedral units and P-centered units including PO4 tetrahedra and HPO3 pseudo-pyramids forming a double layered structure that contains columns of double six-membered rings. The diprotonated 1-(2-Aminoethyl) piperazine molecules reside in the interlayer region and interact with the inorganic network through H-bonds. (C) 2004 Elsevier Inc. All rights reserved.

引用

页码：2518 / 2522

页数：5

共 40 条

[1] HYDROTHERMAL SYNTHESIS AND CHARACTERIZATION OF 2- AND 3-DIMENSIONAL SOLIDS OF THE OXOVANADIUM(IV)-PHOSPHITE SYSTEM - THE STRUCTURES OF [HN(ME)(CH2CH2)(2)N(ME)H]-[(VO)(4)(OH)(2)(HPO3)(4)], [H2N(CH2CH2)(2)NH2][(VO)(3)(HPO3)(4)(H2O)(2)], AND [VO(HPO3)(H2O)]
BONAVIA, G
DEBORD, J
HAUSHALTER, RC
ROSE, D
ZUBIETA, J
[J]. CHEMISTRY OF MATERIALS, 1995, 7 (11) : 1995 - &
[2] Cheetham AK, 1999, ANGEW CHEM INT EDIT, V38, P3268, DOI 10.1002/(SICI)1521-3773(19991115)38:22<3268::AID-ANIE3268>3.0.CO
[3] 2-U
[4] Formation of one-, two-, and three-dimensional open-framework zinc phosphates in the presence of a tetramine
Choudhury, A
Natarajan, S
Rao, CNR
[J]. INORGANIC CHEMISTRY, 2000, 39 (19) : 4295 - 4304
[5] Hydrothermal synthesis and structural characterization of an organically-templated zincophosphite:: [C4N2H12]0.5 • [Zn3(HPO3)4] • H3O
Dong, WJ
Li, GH
Shi, Z
Fu, WS
Zhang, D
Chen, XB
Dai, ZM
Wang, L
Feng, SH
[J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2003, 6 (06) : 776 - 780
[6] Two new three-dimensional vanadium(III) and iron(III) phosphites templated by ethylenediamine:: (C2H10N2)0.5[M(HPO3)2]• ab initio structure determination, spectroscopic, and magnetic properties
Fernández, S
Mesa, JL
Pizarro, JL
Lezama, L
Arriortua, MI
Rojo, T
[J]. CHEMISTRY OF MATERIALS, 2002, 14 (05) : 2300 - 2307
[7] Fernández S, 2002, ANGEW CHEM INT EDIT, V41, P3683, DOI 10.1002/1521-3773(20021004)41:19<3683::AID-ANIE3683>3.0.CO
[8] 2-J
[9] A new layered inorganic-organic hybrid manganese(II) phosphite:: (C2H10N2) [Mn3(HPO3)4].: Hydrothermal synthesis, crystal structure, and spectroscopic and magnetic properties
Fernández, S
Mesa, JL
Pizarro, JL
Lezama, L
Arriortua, MI
Olazcuaga, R
Rojo, T
[J]. CHEMISTRY OF MATERIALS, 2000, 12 (08) : 2092 - 2098
[10] Hydrothermal synthesis and characterization of organically templated zincophosphites with two- and three-dimensional structures, [CH3CH(NH3)CH2NH3] • [Zn2(HPO3)3] • H2O and [H3N(CH2)6NH3] • [Zn3(HPO3)4]
Fu, WS
Shi, Z
Zhang, D
Li, GH
Dai, ZM
Chen, XB
Feng, SH
[J]. JOURNAL OF SOLID STATE CHEMISTRY, 2003, 174 (01) : 11 - 18

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