A tetrahedrally coordinated L3Fe-Nx platform that accommodates terminal nitride (FeIVN) and dinitrogen (FeI-N2-FeI) ligands

被引：299

作者：

Betley, TA ^{[1
]}

Peters, JC ^{[1
]}

机构：

[1] CALTECH, Div Chem & Chem Engn, Arnold & Mabel Beckman Lab Chem Synth, Pasadena, CA 91125 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2004年 / 126卷 / 20期

关键词：

D O I：

10.1021/ja048713v

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A tetrahedrally coordinated L3Fe-Nx platform that accommodates both terminal nitride (L3FeIV≡N) and dinitrogen (L3FeI-N2-FeIL3) functionalities is described. The diamagnetic L3FeIV≡N species featured has been characterized in solution under ambient conditions by multinuclear NMR (1H, 31P, and 15N) and infrared spectroscopy. The electronic structure of the title complex has also been explored using DFT. The terminal nitride complex oxidatively couples to generate the previously reported L3FeI-N2-FeIL3 species. This reaction constitutes a six-electron transformation mediated by two iron centers. Reductive protonation of the nitride complex releases NH3 as a significant reaction product. Copyright © 2003 American Chemical Society.

引用

页码：6252 / 6254

页数：3

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