A synthesis and luminescence study of Ir(ppz)3 for organic light-emitting devices

被引:36
作者
Nam, EJ
Kim, JH
Kim, BO
Kim, SM
Park, NG
Kim, YS
Kim, YK
Ha, Y [1 ]
机构
[1] Hongik Univ, Coll Engn, Dept Sci, Seoul, South Korea
[2] Hongik Univ, Dept Elect Engn, Seoul, South Korea
[3] Hongik Univ, Sci & Technol Res Inst, Seoul, South Korea
关键词
D O I
10.1246/bcsj.77.751
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Tris(1-phenyl-kappaC(1) -pyrazolato-kappaN(2))iridium (lr(ppz)(3)) was prepared and its luminescence properties were investigated for the application to organic light-emitting devices (OLEDs). The photoluminescence (PL) spectra of Ir(ppz)(3) in dichloromethane showed a peak at 437 nm at room temperature. The luminescent lifetime of an lr(ppz)(3) film doped in CBP was found to be 2 18 ns. which indicated that its emission is phosphorescent. OLEDs were fabricated with doped films of lr(ppz)(3) in several hosts. and the electroluminescence (EL) peak was observed at 450 nm. The luminance of OLEDs was pure blue. with the CIE coordinates of x = 0. 158, y = 0. 139 at 100 cd/m(2) , but luminous efficiencies were low since the LUMO of Ir(ppz)(3) is higher than those of the hosts used.
引用
收藏
页码:751 / 755
页数:5
相关论文
共 27 条
[1]   High efficiency single dopant white electrophosphorescent light emitting diodes [J].
Adamovich, V ;
Brooks, J ;
Tamayo, A ;
Alexander, AM ;
Djurovich, PI ;
D'Andrade, BW ;
Adachi, C ;
Forrest, SR ;
Thompson, ME .
NEW JOURNAL OF CHEMISTRY, 2002, 26 (09) :1171-1178
[2]   Phosphorescent materials for application to organic light emitting devices [J].
Baldo, MA ;
Thompson, ME ;
Forrest, SR .
PURE AND APPLIED CHEMISTRY, 1999, 71 (11) :2095-2106
[3]   High-efficiency fluorescent organic light-emitting devices using a phosphorescent sensitizer [J].
Baldo, MA ;
Thompson, ME ;
Forrest, SR .
NATURE, 2000, 403 (6771) :750-753
[4]   Treatment of electronic excitations within the adiabatic approximation of time dependent density functional theory [J].
Bauernschmitt, R ;
Ahlrichs, R .
CHEMICAL PHYSICS LETTERS, 1996, 256 (4-5) :454-464
[5]   DENSITY-FUNCTIONAL THERMOCHEMISTRY .3. THE ROLE OF EXACT EXCHANGE [J].
BECKE, AD .
JOURNAL OF CHEMICAL PHYSICS, 1993, 98 (07) :5648-5652
[6]   Synthesis and characterization of phosphorescent cyclometalated platinum complexes [J].
Brooks, J ;
Babayan, Y ;
Lamansky, S ;
Djurovich, PI ;
Tsyba, I ;
Bau, R ;
Thompson, ME .
INORGANIC CHEMISTRY, 2002, 41 (12) :3055-3066
[7]   Molecular excitation energies to high-lying bound states from time-dependent density-functional response theory: Characterization and correction of the time-dependent local density approximation ionization threshold [J].
Casida, ME ;
Jamorski, C ;
Casida, KC ;
Salahub, DR .
JOURNAL OF CHEMICAL PHYSICS, 1998, 108 (11) :4439-4449
[8]  
Chan SC, 2001, CHEM-EUR J, V7, P4180, DOI 10.1002/1521-3765(20011001)7:19<4180::AID-CHEM4180>3.0.CO
[9]  
2-9
[10]   Metal chelates as emitting materials for organic electroluminescence [J].
Chen, CH ;
Shi, JM .
COORDINATION CHEMISTRY REVIEWS, 1998, 171 :161-174