Interpenetrating Polyhedral MOF with a Primitive Cubic Network Based on Supermolecular Building Blocks Constructed of a Semirigid C3-Symmetric Carboxylate Ligand

被引：84

作者：

Zhao, Xiaoliang ^{[1
]}

He, Haiyan ^{[1
]}

Hu, Tuoping ^{[1
,2
]}

Dai, Fangna ^{[1
]}

Sun, Daofeng ^{[1
]}

机构：

[1] Shandong Univ, Minist Educ, Sch Chem & Chem Engn, Key Lab Colloid & Interface Chem, Jinan 250100, Peoples R China

[2] N Univ China, Dept Chem, Taiyuan 030051, Shanxi, Peoples R China

来源：

INORGANIC CHEMISTRY | 2009年 / 48卷 / 17期

关键词：

METAL-ORGANIC FRAMEWORK; SORPTION PROPERTIES; LARGE CAVITIES; LUMINESCENT; DESIGN; ADSORPTION; CHANNELS; SITES; NET;

D O I：

10.1021/ic901004m

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

By application of a newly developed C-3-symmetric tripodal carboxylate ligand, 1,1',1 ''-(benzene-1,3,5-triyl)tripiperidine-4-carboxylic acid (H(3)BTPCA) to assemble with zinc ion in the presence of pyridine, a novel 2-fold interpenetrating polyhedral metal-organic framework with a primitive cubic network based on supermolecular building blocks (SBBs) has been synthesized. The basic paddlewheel secondary building units (SBUs) are connected by deprotonated BTPCA ligands to generate an octahedron as the SBB, which is further connected through the six vertexes by sharing the paddlewheel SBUs to give rise to the 3D primitive cubic network.

引用

页码：8057 / 8059

页数：3

共 52 条

[1] A cubic (3,4)-connected net with large cavities in solvated [Cu-3(tpt)(4)](ClO4)(3) (tpt=2,4,6-tri(4-pyridyl)-1,3,5-triazine) [J].