Di(adamant-1-yl)- and Di(adamant-2-yl)thiophosphoric Acids and Their Triethylammonium Salts in Alkylation Reactions

被引：0

作者：

Yurchenko, R. I. ^{[1
]}

Klimko, Yu. M. ^{[1
]}

Esipenko, A. A. ^{[1
]}

Butova, E. D. ^{[1
]}

Yurchenko, A. G. ^{[1
]}

机构：

[1] Natl Tech Univ Ukraine, Kiev Polytech Inst, UA-03056 Kiev, Ukraine

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2009年 / 79卷 / 08期

关键词：

PHOSPHORYLATED ADAMANTANES;

D O I：

10.1134/S1070363209080076

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

By reaction of di(adamant-1-yl) and di(adamant-2-yl) phosphites with sulfur in the presence of triethylamine diadamantylthiophosphoric acid triethylammonium salts were obtained. The latter by the action of hydrochloric acid were converted into free thiophosphoric acids and by the reaction of alkylation into the respective triesters which have thionic structure. Applicability in such reactions also of triethylammonium salts of diadamantyldithiophosphoric acids was demonstrated.

引用

页码：1632 / 1634

页数：3