Synthesis, characterization, and modelling of novel multifunctional acryloyl-based monomers: An experimental and computational study

被引：3
|
作者：
Patras, G
Qiao, GG
Solomon, DH [1 ]
Koch, R
机构：
[1] Univ Melbourne, Dept Chem Engn, Polymer Sci Grp, Parkville, Vic 3010, Australia
[2] Carl von Ossietzky Univ Oldenburg, Fachbereich Chem, D-26111 Oldenburg, Germany
来源：
AUSTRALIAN JOURNAL OF CHEMISTRY | 2002年 / 55卷 / 10期
关键词：
D O I：
10.1071/CH01082
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Several novel multifunctional monomers with at least three reactive N-acryloyl double bonds have been synthesized and fully characterized. Quantum-chemical calculations and nuclear magnetic resonance (NMR) spectroscopy have been used to predict the structural dissymmetry of these monomers: the simulation of conformers and the NMR spectrum of monomer (3) allows the explanation of the observed C-13 NMR spectra as well as a comparison of the performance of several methods for calculating chemical shifts.
引用
收藏
页码：675 / 680
页数：6
相关论文
共 50 条
  • [41] Synthesis and characterization of novel organotin carboxylate maleimide monomers and copolymers
    Gaina, C.
    Gaina, V.
    EXPRESS POLYMER LETTERS, 2009, 3 (06): : 352 - 358
  • [42] Synthesis and characterization of novel organotin monomers and copolymers and their antibacterial activity
    Al-Muaikel, NS
    Al-Diab, SS
    Al-Salamah, AA
    Zaid, AMA
    JOURNAL OF APPLIED POLYMER SCIENCE, 2000, 77 (04) : 740 - 745
  • [43] Synthesis and Characterization of Curable Methacrylate-Based Monomers
    Ghaemy, Mousa
    Bekhradnia, Sara
    JOURNAL OF APPLIED POLYMER SCIENCE, 2010, 117 (01) : 467 - 472
  • [44] Synthesis, polymerization, and characterization of sulfonamide based bifunctional monomers
    Hall, Brady
    Meyer, Luke
    Munch, Jessica
    Fossum, Eric
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2016, 251
  • [45] Synthesis, characterization, and copolymerization of a series of novel acid monomers based on sulfonimides for proton conducting membranes
    Rahman, MK
    Aiba, G
    Susan, AB
    Sasaya, Y
    Ota, K
    Watanabe, M
    MACROMOLECULES, 2004, 37 (15) : 5572 - 5577
  • [46] Synthesis and Characterization of Novel Quaternary Ammonium Urethane-Dimethacrylate Monomers-A Pilot Study
    Chroszcz, Marta W.
    Barszczewska-Rybarek, Izabela M.
    INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES, 2021, 22 (16)
  • [47] Synthesis and cationic photopolymerization of novel monomers based on dicyclopentadiene
    Crivello, JV
    Song, SY
    CHEMISTRY OF MATERIALS, 2000, 12 (12) : 3674 - 3680
  • [48] Synthesis, characterization, and computational study of the supramolecular arrangement of a novel cinnamic acid derivative
    Oliveira, S. S.
    Santin, L. G.
    Almeida, L. R.
    Malaspina, L. A.
    Lariucci, C.
    Silva, J. F.
    Fernandes, W. B.
    Aquino, G. L. B.
    Gargano, R.
    Camargo, A. J.
    Napolitano, H. B.
    JOURNAL OF MOLECULAR MODELING, 2017, 23 (02)
  • [49] Synthesis, characterization, and computational study of the supramolecular arrangement of a novel cinnamic acid derivative
    S. S. Oliveira
    L. G. Santin
    L. R. Almeida
    L. A. Malaspina
    C. Lariucci
    J. F. Silva
    W. B. Fernandes
    G. L. B. Aquino
    R. Gargano
    A. J. Camargo
    H. B. Napolitano
    Journal of Molecular Modeling, 2017, 23
  • [50] Experimental characterization of structural features during radical chain homopolymerization of multifunctional monomers prior to macroscopic gelation
    Hutchison, JB
    Lindquist, AS
    Anseth, KS
    MACROMOLECULES, 2004, 37 (10) : 3823 - 3831
12345