Synthesis, characterization, and modelling of novel multifunctional acryloyl-based monomers: An experimental and computational study

被引:3
|
作者
Patras, G
Qiao, GG
Solomon, DH [1 ]
Koch, R
机构
[1] Univ Melbourne, Dept Chem Engn, Polymer Sci Grp, Parkville, Vic 3010, Australia
[2] Carl von Ossietzky Univ Oldenburg, Fachbereich Chem, D-26111 Oldenburg, Germany
关键词
D O I
10.1071/CH01082
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Several novel multifunctional monomers with at least three reactive N-acryloyl double bonds have been synthesized and fully characterized. Quantum-chemical calculations and nuclear magnetic resonance (NMR) spectroscopy have been used to predict the structural dissymmetry of these monomers: the simulation of conformers and the NMR spectrum of monomer (3) allows the explanation of the observed C-13 NMR spectra as well as a comparison of the performance of several methods for calculating chemical shifts.
引用
收藏
页码:675 / 680
页数:6
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