Mixed Langmuir-Blodgett monolayers containing carboxylic ionophores.: Application to Na+ and Ca2+ ISFET-based sensors

被引:22
|
作者
Rochefeuille, S
Jimenez, C
Tingry, S
Seta, P
Desfours, JP
机构
[1] Univ Montpellier 2, Lab Genie Proc, F-34095 Montpellier 5, France
[2] CSIC, IMB CNM, Inst Microelect Barcelona, E-08193 Barcelona, Spain
[3] CNRS, UMR 5635, Lab Mat & Proc Membranaires, F-34293 Montpellier 5, France
关键词
Langmuir-Blodgett monolayers; monensin; calcimycin; ISFETs;
D O I
10.1016/S0928-4931(02)00056-5
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Novel ISFET devices coated with ultrathin membranes are suitable for cation detection in liquids. Deposition of Na+-ion and Ca2+-ion sensitive Langmuir-Blodgett films onto ISFET surfaces has been achieved. In this work, we present first experimental results about ISFET devices coated with LB mixed films. The sensitive material is a carboxylic ionophore (monensin or calcimycin) included in a phospholipid matrix. The sensors showed a linear response with a slope of 19 mV/pNa in the range 10(-2)/10(-6) mol/l and a slope 23 mV/pCa in the range of 10(-2)/10(-4) mol/l. The results have demonstred the transferability of mixed films onto structured semiconductor devices like ISFETs. This response let us expect further improvements. (C) 2002 Elsevier Science B.V. All rights reserved.
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页码:43 / 46
页数:4
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