Iodination of tricyclo[4.1.0.02,7]heptane in the presence of external nucleophiles

被引：5

作者：

Vasin, VA ^{[1
]}

Semenov, AV

Razin, VV

机构：

[1] Mordovian NP Ogarev State Univ, Saransk 430000, Russia

[2] St Petersburg State Univ, St Petersburg, Russia

来源：

RUSSIAN JOURNAL OF ORGANIC CHEMISTRY | 2002年 / 38卷 / 06期

关键词：

D O I：

10.1023/A:1020382903063

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Tricyclo[4.1.0.0(2.7)]heptane reacted with iodine, N-iodosuccinimide, and iodine monochloride in the presence of external nucleophiles yielding products of conjugate endo,syn addition at the central C-1-C-7 bond. The mechanism of these chemo- and stereoselective reactions is discussed.

引用

页码：803 / 809

页数：7

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