Iodination of tricyclo[4.1.0.02,7]heptane in the presence of external nucleophiles

被引：5
|
作者：
Vasin, VA [1 ]
Semenov, AV
Razin, VV
机构：
[1] Mordovian NP Ogarev State Univ, Saransk 430000, Russia
[2] St Petersburg State Univ, St Petersburg, Russia
来源：
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY | 2002年 / 38卷 / 06期
关键词：
D O I：
10.1023/A:1020382903063
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Tricyclo[4.1.0.0(2.7)]heptane reacted with iodine, N-iodosuccinimide, and iodine monochloride in the presence of external nucleophiles yielding products of conjugate endo,syn addition at the central C-1-C-7 bond. The mechanism of these chemo- and stereoselective reactions is discussed.
引用
收藏
页码：803 / 809
页数：7
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