Me-bipam for Enantioselective Ruthenium (II)-Catalyzed Arylation of Aldehydes with Arylboronic Acids

被引：120

作者：

Yamamoto, Yasunori ^{[1
]}

Kurihara, Kazunori ^{[1
]}

Miyaura, Norio ^{[1
]}

机构：

[1] Hokkaido Univ, Grad Sch Engn, Div Chem Proc Engn, Sapporo, Hokkaido 0608628, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 24期

关键词：

aldehydes; asymmetric catalysis; boron; nucleophilic addition; ruthenium; RHODIUM-CATALYZED ADDITION; CARBONYL-COMPOUNDS; ALPHA; BETA-UNSATURATED KETONES; ASYMMETRIC-SYNTHESIS; ORGANOBORONIC ACIDS; AROMATIC-ALDEHYDES; 1,2-ADDITION; 1,4-ADDITION; COMPLEXES; ARYL;

D O I：

10.1002/anie.200901395

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ligand design by-pam: A ruthenium-catalyzed asymmetric arylation of aldehydes with arylboronic acids has been developed, giving chiral diarylmethanols in good yields. The use of a chiral bidentate phosphoramidite ligand ((R,R)-Me-bipam) led to excellent enantioselectivities. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：4414 / 4416

页数：3

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