Rheology of phosphorylated cashew nut shell liquid prepolymer modified natural rubber

被引:0
作者
Menon, ARR [1 ]
Pillai, CKS [1 ]
Bhattacharya, AK [1 ]
Nando, GB [1 ]
Gupta, BR [1 ]
机构
[1] Indian Inst Technol, Ctr Rubber Technol, Kharagpur 721302, W Bengal, India
来源
KAUTSCHUK GUMMI KUNSTSTOFFE | 2000年 / 53卷 / 1-2期
关键词
melt rheology; cashew nut shell liquid; phosphorylated prepolymer; natural rubber; plasticizer; processability; Monsanto processability tester;
D O I
暂无
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Natural Rubber (NR) modified with Phosphorylated Cashew Nut Shell Liquid prepolymer (PCNSL) or with an aromatic oil shows an increased pseudoplasticity index and a decreased consistency index. The apparent melt viscosity of these systems decreases with increased temperature and shear rate and the activation energy for melt flow also decreases with rate of shear. Further, the reduction in die-swell ratio during extrusion of the PCNSL modified NR indicates a reduction in melt elasticity compared to the unmodified sample. Good compatibility between NR and PCNSL is indicated by the decrease of the principal normal stress difference of NR in presence of PCNSL.
引用
收藏
页码:35 / 41
页数:7
相关论文
共 44 条
[1]   DIE WALL RESTRICTION ON ELASTIC SHEAR DEFORMATION IN VISCOELASTIC FLOW OF POLYMER MELT [J].
ARAI, T ;
AOYAMA, H .
TRANSACTIONS OF THE SOCIETY OF RHEOLOGY, 1963, 7 :333-355
[2]  
BEARDSLEY KP, 1984, J ELAST PLAST, V16, P339
[3]  
BLAKE WT, 1969, AM LAB SEP, P42
[4]  
BRYDSON JA, 1981, FLOW PROPERTIES POLY, P42
[5]  
Chattaraj PP, 1997, KAUT GUMMI KUNSTST, V50, P34
[6]  
CHEREMISINOFF NP, 1987, POLYM MIXING EXTRUSI, P7
[7]   RHEOLOGICAL BEHAVIOR OF POLYMER BLENDS [J].
CHUANG, HK ;
HAN, CD .
JOURNAL OF APPLIED POLYMER SCIENCE, 1984, 29 (06) :2205-2229
[8]  
Coulson JM, 1971, CHEM ENG, V3
[9]  
GRAESSLEY WW, 1969, FALL M SOC RHEOL ST
[10]   RHEOLOGICAL BEHAVIOR OF COMPATIBLE POLYMER BLENDS .1. BLENDS OF POLY(STYRENE-CO-ACRYLONITRILE) AND POLY(EPSILON-CAPROLACTONE) [J].
HAN, CD ;
YANG, HH .
JOURNAL OF APPLIED POLYMER SCIENCE, 1987, 33 (04) :1199-1220