Determination of cis and trans configurations in pentahydrobenzopyranopyrroles by FT-IR spectroscopy

被引：5

作者：

Bertrand, B ^{[1
]}

Nisole, C ^{[1
]}

Drancourt, JM ^{[1
]}

Dubuffet, T ^{[1
]}

Bouchet, JP ^{[1
]}

Volland, JP ^{[1
]}

机构：

[1] INST RECH SERVIER,F-92150 SURESNES,FRANCE

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 1996年 / 52卷 / 14期

关键词：

Bohlmann bands; cis-trans configuration; beta; beta'-disubstituted pyrrolidines; FT-IR spectroscopy; pentahydrobenzopyranopyrroles;

D O I：

10.1016/S0584-8539(96)01751-5

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

A method of distinguishing cis and trans isomers in polyheterocycles containing beta,beta'-disubstituted pyrrolidines is described. It is based on the relative absorbance of the Bohlmann bands and the normal symmetric CH stretching bands. The method is applied using FT-IR spectroscopy in solution and coupled with gas chromatography. An interpretation is given, with the help of molecular computing.

引用

页码：1921 / 1923

页数：3

共 6 条

[1] LUPINEN-ALKALOIDE .8. ZUR KONFIGURATIONSBESTIMMUNG VON CHINOLIZIDIN-DERIVATEN [J].