Studies of alkaline solid polymer electrolyte and mechanically alloyed polycrystalline Mg2Ni for use in nickel metal hydride batteries

被引：41

作者：

Mohamad, AA

Mohamed, NS

Alias, Y

Arof, AK ^{[1
]}

机构：

[1] Univ Malaya, Dept Phys, Kuala Lumpur 50603, Malaysia

[2] Univ Malaya, Ctr Fdn Studies Sci, Kuala Lumpur 50603, Malaysia

[3] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 2002年 / 337卷

关键词：

alloys; hydrogen absorbing materials; electrode materials; electrochemical reaction;

D O I：

10.1016/S0925-8388(01)01916-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Ni-MH cells comprising PVA-KOH solid polymer electrolyte and mechanically alloyed Mg2Ni as the negative electrode have been fabricated. The alkaline solid polymer electrolyte with PVA:KOH wt.% ratio of 60:40 exhibits the highest room temperature ionic conductivity of 8.5 x 10(-4) S cm(-1). This sample is mostly amorphous. The cell was charged at a constant current of 10 mA and discharged at 0.1 mA. The discharge characteristics improved upon cycling and the plateau voltage maintained above 1.2 V for similar to10 h. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：208 / 213

页数：6

共 3 条

[1] Substitution of nickel in Mg2Ni and its hydride with elements from groups XIII and XIV: An ab initio study
Kana, T.
Cermak, J.
Kral, L.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2021, 46 (29) : 15691 - 15701
[2] Effects of sintering on composite metal hydride alloy of Mg2Ni and TiNi synthesized by mechanical alloying
Han, SS
Goo, NH
Lee, KS
JOURNAL OF ALLOYS AND COMPOUNDS, 2003, 360 (1-2) : 243 - 249
[3] Ti-V-Cr-Ni alloys as high capacity negative electrode active materials for use in nickel-metal hydride batteries
Inoue, Hiroshi
Kotani, Norihiro
Chiku, Masanobu
Higuchi, Eiji
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2016, 41 (23) : 9939 - 9947

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