Redox-active phosphines: synthesis and crystal structures of palladium(II) complexes of a metallaphosphine in two different oxidation states

被引：3

作者：

Tohme, Ayham ^{[1
]}

Labouille, Stephanie ^{[2
]}

Roisnel, Thierry ^{[1
]}

Dorcet, Vincent ^{[1
]}

Carmichael, Duncan ^{[2
]}

Paul, Frederic ^{[1
]}

机构：

[1] Univ Rennes 1, CNRS UMR 6226, Inst Sci Chim Rennes, F-35042 Rennes, France

[2] Ecole Polytech, CNRS, UMR 7653, Lab Heteroelments & Coordinat, F-91128 Palaiseau, France

来源：

DALTON TRANSACTIONS | 2014年 / 43卷 / 19期

关键词：

FERROCENYLETHYNYL PHOSPHANES; BINUCLEAR PALLADIUM(II); BOND FORMATION; LIGANDS; SYSTEMATICS; ACTIVATION; DESIGN; CC;

D O I：

10.1039/c4dt00455h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The redox-active metallaphosphine [Fe(dppe)(eta(5)-C5Me5)(C=CPPh2)] reacts with [Pd(1,5-cod) Cl-2] to give mono-and bis-phosphine coordinated palladium centres as a function of stoichiometry, and these complexes provide a stable redox-active platform which allows reversible one-electron {Fe(II)-> Fe(III)(+)} oxidations within the palladium coordination sphere.

引用

页码：7002 / 7005

页数：4

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