H2O-controlled selective thiocyanation and alkenylation of ketene dithioacetals under electrochemical oxidation

被引：47

作者：

Wen, Jiangwei ^{[1
]}

Zhang, Longfei ^{[1
]}

Yang, Xiaoting ^{[1
]}

Niu, Cong ^{[1
]}

Wang, Shuangfeng ^{[1
]}

Wei, Wei ^{[1
]}

Sun, Xuejun ^{[1
]}

Yang, Jianjing ^{[1
]}

Wang, Hua ^{[1
]}

机构：

[1] Qufu Normal Univ, Coll Chem & Chem Engn, Inst Med & Mat Appl Technol, Qufu 273165, Shandong, Peoples R China

来源：

GREEN CHEMISTRY | 2019年 / 21卷 / 13期

关键词：

CYCLIZATION REACTIONS; C-3; THIOCYANATION; FACILE SYNTHESIS; SULFINIC ACIDS; ALKENES; EFFICIENT; ACCESS; ALKYNES; TRIFLUOROMETHYLTHIOCYANATION; THIOCYANOOXYGENATION;

D O I：

10.1039/c9gc01351b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Efficient and H2O-controlled selective thiocyanation and alkenylation of internal olefins, to afford tetrasubstituted olefins under electrochemical oxidation, has been successfully developed. This transformation can present a critical feature wherein neither exogenous oxidants nor catalysts are required. Notably, such an electrochemical oxidation-based synthetic strategy exhibits excellent tolerance towards functional groups and can be easily scaled up with good efficiency.

引用

页码：3597 / 3601

页数：5

共 45 条

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