Synthesis, crystal structure and spectroscopic studies of a mixed ligand copper (II) complex:: trans-bis(succinimidato)-bis(benzylamino)Cu(II)

被引：0

作者：

Tas, Murat ^{[1
]}

Saracoglu, Hanife

Bati, Humeyra

Caliskan, Nezihe

Buyukgungor, Orhan

机构：

[1] Giresun Univ, Fac Art & Sci, Dept Chem, TR-28049 Giresun, Turkey

[2] Rize Univ, Fac Art & Sci, Dept Phys, TR-53100 Rize, Turkey

[3] Ondokuz Mayis Univ, Fac Art & Sci, Dept Chem, TR-55139 Kurupelit, Turkey

[4] Ondokuz Mayis Univ, Fac Art & Sci, Dept Phys, TR-55139 Kurupelit, Turkey

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2006年 / 61卷 / 08期

关键词：

succinimide; succinimidato; mixed ligand complex;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The molecules of the title compound, [Cu(C11H13N2O2)(2)], lie across centres of inversion in space group P2(1)/c and are linked by intermolecular N-H center dot center dot center dot O and C-H center dot center dot center dot O hydrogen bonds. The central Cu atom has a slightly distorted square-planar coordination comprised of four N atoms. Cu-N bond distances are 1.975(2) and 2.020(2) angstrom. The interplanar angle between the phenyl and succinimidato ring is 87.34(10)degrees.

引用

页码：979 / 982

页数：4

共 14 条

[1] Diastereomers of copper(II) complexes exhibiting difference in coordination geometry by R- or S-1-phenylethylamine ligands in the solid state and structural conversion of crystals into solutions [J].

Akitsu, T ;

Komorita, S ;

Tamura, H .

INORGANICA CHIMICA ACTA, 2003, 348 :25-32

[2] High axial coordination in a cis-coordinated succinimidatocopper(II) complex [J].

Akitsu, T ;

Komorita, S .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2002, 75 (04) :767-768

[3] Preparation and crystal structures of trans-bis(imidato)bis(1,2-diphenylethylamine)copper(II) complexes (imidato=5,5-diphenylhydantoinato and succinimidato).: Particular boundary cases of coordination geometry and monodentate ligand conformation [J].

Akitsu, T ;

Komorita, S ;

Kushi, Y .

INORGANICA CHIMICA ACTA, 2001, 315 (01) :18-25

[4] Structures and Electronic Spectra of Aquadiiminebis(succinimidato)copper(II) Complexes with Square Pyramidal [CuN4O] Chromophores (Diimine=1,10-Phenanthroline and 2,2′-Bipyridine) [J].

Akitsu, Takashiro ;

Komorita, Seiko ;

Kushi, Yoshihiko .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1999, 72 (03) :447-454

[5] Synthesis, physicochemical investigation and cytotoxic activity of new Pt(II) complexes with hydantoin ligands [J].

Bakalova, A ;

Buyukliev, R ;

Tcholakova, I ;

Momekov, G ;

Konstantinov, S ;

Karaivanova, M .

EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY, 2003, 38 (06) :627-632

[6] ORTEP-3 for Windows - a version of ORTEP-III with a Graphical User Interface (GUI) [J].

Journal of Applied Crystallography, 1997, 30 (pt 5)

[7]

Farrugia L. J., 1999, J. Appl. Crystallogr, V32, P837, DOI DOI 10.1107/S0021889899006020

[8] Vanadium complexes of bioinorganic relevance: Synthesis, magnetic, and spectral studies of some mixed-ligand oxovanadium(IV) complexes having an N, O-donor environment [J].

Maurya, RC ;

Rajput, S .

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 2003, 33 (10) :1877-1894

[9] Inhibition and photo-deinhibition of glutathione (S)-transferase activity by an organometallic complex:: (S)-[3-CpFe(CO)2(η1-N-succinimidato)]glutathione [J].

Salmain, M ;

Jaouen, G ;

Rudolf, B ;

Zakrzewski, J .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1999, 589 (01) :98-102

[10] N-Bromosuccinimide in oxidative addition reactions with palladium(0) and platinum(0) precursors [J].

Serrano, JL ;

Zheng, YF ;

Dilworth, JR ;

Sánchez, G .

INORGANIC CHEMISTRY COMMUNICATIONS, 1999, 2 (09) :407-410

← 1 2 →