Solvatochromism of heteroaromatic compounds: XV. 3-Nitro-1,2,4-triazol-5-ones

被引:2
作者
Vokin, AI [1 ]
Sherstyannikova, LV [1 ]
Krivoruchka, IG [1 ]
Abzaeva, KA [1 ]
Lopyrev, VA [1 ]
Turchaninov, VK [1 ]
机构
[1] Russian Acad Sci, Favorskii Irkutsk Inst Chem, Siberian Div, Irkutsk 664003, Russia
关键词
Hydrogen; Hydrogen Bond; Absorption Band; Electronic Spectrum; Intermolecular Hydrogen Bond;
D O I
10.1023/A:1015416322512
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Effect or the medium oil the parameters of the long-wave absorption band in the electronic spectra of H complexes formed by 3-nitro-1,2,4-triazol-5-one and its N-methyl derivatives with aprotic protophilic solvents was described on a quantitative level using Kamlet-Taft solvatochromic parameters, A weak nonadditivity was revealed in the influence of two kinds of intermolecular hydrogen bonds.
引用
收藏
页码:456 / 459
页数:4
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