Construction and characterization of novel molecular architectures through coordination-driven self-assembly: rhomboid and overlapped double rhomboid

被引：2

作者：

Kim, Jeum-Jong ^{[1
]}

Kwak, Ock Keum ^{[2
,3
]}

Park, Jong Keun ^{[2
,3
]}

Min, Kil Sik ^{[4
,5
]}

Yoon, Yong-Jin ^{[6
]}

机构：

[1] Elect & Telecommun Res Inst, Taejon 305700, South Korea

[2] Gyeongsang Natl Univ, Inst Basic Sci, Dept Chem Educ, Jinju 660701, South Korea

[3] Gyeongsang Natl Univ, Inst Basic Sci, Res Inst Nat Sci, Jinju 660701, South Korea

[4] Kyungpook Natl Univ, Dept Chem Educ, Taegu 702701, South Korea

[5] Kyungpook Natl Univ, Green Nano Mat Res Ctr, Taegu 702701, South Korea

[6] Gyeongsang Natl Univ, Grad Sch Mol Mat & Nanochem, Res Inst Nat Sci, Dept Chem, Jinju 660701, South Korea

来源：

JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY | 2014年 / 79卷 / 3-4期

关键词：

Molecular architecture; Self-assembly; Ligand; Platinum; Rhomboid; Supramolecule; RATIONAL DESIGN; TRIGONAL PRISMS; METALLODENDRIMERS; DISCRETE; SYMMETRY; ENCAPSULATION; RECOGNITION; CHEMISTRY; CATALYSIS; ROTATION;

D O I：

10.1007/s10847-013-0373-3

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The potentially tridentate ligands 4-(6-(pyridin-4-yl)pyridin-2-yl)pyridine (4) and 3-(6-(pyridin-3-yl)-pyridin-2-yl)pyridine (5) have been prepared and characterized. From the self-assembly of 4 or 5 and 2,9-bis[trans-Pt(PEt3)(2)(NO3)]phenanthrene (6), two supramolecular platinum-based macrocycles with rhomboid (7) and overlapped double rhomboid (8) structures have been constructed. Compounds 7 and 8 are formed in different shapes due to the different nitrogen positions (meta and para) of the ligands 4 and 5, respectively. Both supramolecules are characterized by multinuclear NMR and electrospray ionization mass spectroscopies.

引用

页码：495 / 502

页数：8

共 61 条

[1] Self-recognition in the coordination driven self-assembly of 2-D polygons [J].

Addicott, C ;

Das, N ;

Stang, PJ .

INORGANIC CHEMISTRY, 2004, 43 (17) :5335-5338

[2]

Akiyama R, 2001, ANGEW CHEM INT EDIT, V40, P3469, DOI 10.1002/1521-3773(20010917)40:18<3469::AID-ANIE3469>3.0.CO

[3]

2-T

[4]

Baxter PNW, 1999, CHEM-EUR J, V5, P102

[5] Characterization of Self-Assembled Metallodendrimers in Solution, in the Gas Phase, and at Air/Solid Interfaces [J].

Baytekin, H. Tarik ;

Sahre, Mario ;

Rang, Alexander ;

Engeser, Marianne ;

Schulz, Andrea ;

Schalley, Christoph A. .

SMALL, 2008, 4 (10) :1823-1834

[6] Coordination-driven face-directed self-assembly of trigonal prisms. Face-based conformational chirality [J].

Caskey, Douglas C. ;

Yamamoto, Takuya ;

Addicott, Chris ;

Shoemaker, Richard K. ;

Vacek, Jaroslav ;

Hawkridge, Adam M. ;

Muddiman, David C. ;

Kottas, Gregg S. ;

Michl, Josef ;

Stang, Peter J. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (24) :7620-7628

[7] Supermolecules by design [J].

Caulder, DL ;

Raymond, KN .

ACCOUNTS OF CHEMICAL RESEARCH, 1999, 32 (11) :975-982

[8] The rational design of high symmetry coordination clusters [J].

Caulder, DL ;

Raymond, KN .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (08) :1185-1200

[9] Supramolecular Coordination: Self-Assembly of Finite Two- and Three-Dimensional Ensembles [J].

Chakrabarty, Rajesh ;

Mukherjee, Partha Sarathi ;

Stang, Peter J. .

CHEMICAL REVIEWS, 2011, 111 (11) :6810-6918

[10] Self-assembly of flexible supramolecular metallacyclic ensembles: Structures and adsorption properties of their nanoporous crystalline frameworks [J].

Chatterjee, B ;

Noveron, JC ;

Resendiz, MJE ;

Liu, J ;

Yamamoto, T ;

Parker, D ;

Cinke, M ;

Nguyen, CV ;

Arif, AM ;

Stang, PJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (34) :10645-10656

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