Synthesis and structure of a Mn-III(OH) complex generated from dioxygen

被引:47
作者
Shirin, Z
Young, VG
Borovik, AS
机构
[1] UNIV KANSAS,DEPT CHEM,LAWRENCE,KS 66045
[2] UNIV MINNESOTA,DEPT CHEM,MINNEAPOLIS,MN 55455
关键词
D O I
10.1039/a703395h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Dioxygen activation at room temperature by a new Mn-II complex having a cavity motif yields a monomeric Mn-III complex with a terminally bonded hydroxo ligand whose oxygen atom is derived from O-2.
引用
收藏
页码:1967 / 1968
页数:2
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