Effect of boron oxide on the cubic-to-monoclinic phase transition in yttria-stabilized zirconia

被引:27
作者
de Florio, DZ [1 ]
Muccillo, R [1 ]
机构
[1] IPEN, CCTM, Ctr Multidisciplinar Desenvolvimento Mat Ceram, BR-05422970 Sao Paulo, SP, Brazil
基金
巴西圣保罗研究基金会;
关键词
phase transitions;
D O I
10.1016/j.materresbull.2004.04.017
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Specimens of yttria fully stabilized zirconia with different amounts of boron oxide have been studied by X-ray diffraction at room temperature and at higher temperatures up to 1250 degreesC. A boron oxide-assisted cubic-to-monoclinic phase transformation was determined in the temperature range 800-1250 degreesC. In situ high temperature X-ray diffraction experiments gave evidences of the dependence of the phase transformation on the heating rate. The possibility of tuning the cubic-monoclinic phase ratio by suitable addition of boron oxide before pressing and sintering is proposed. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1539 / 1548
页数:10
相关论文
共 20 条
[1]   DESTABILIZATION OF CALCIA STABILIZED ZIRCONIA [J].
ANANTHAPADMANABHAN, PV ;
MENON, SB ;
VENKATRAMANI, N ;
ROHATGI, VK .
JOURNAL OF MATERIALS SCIENCE, 1989, 24 (12) :4432-4436
[2]  
BUCHANAN RC, 1983, J AM CERAM SOC, V66, pC20, DOI 10.1111/j.1151-2916.1983.tb09998.x
[3]   A new destabilization phenomenon in fully-stabilized zirconia [J].
Guo, X .
JOURNAL OF MATERIALS SCIENCE LETTERS, 1996, 15 (01) :38-39
[4]  
HAGENMULLER P, 1978, SOLID ELECTROLYTES T
[5]  
HEUER AH, 1988, ADV CERAMICS A, V24
[6]   THE CRYSTAL STRUCTURE OF BADDELEYITE (MONOCLINIC ZRO2) [J].
MCCULLOUGH, JD ;
TRUEBLOOD, KN .
ACTA CRYSTALLOGRAPHICA, 1959, 12 (07) :507-511
[7]   CERAMIC FUEL-CELLS [J].
MINH, NQ .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1993, 76 (03) :563-588
[8]   Synthesis of reactive ceramic powders by the citrate technique [J].
Muccillo, R ;
Muccillo, ENS ;
Cosentino, IC ;
França, YV ;
Fonseca, FC ;
Saito, NH .
ADVANCED POWDER TECHNOLOGY, 1999, 299-3 :80-90
[9]  
RIGDON MA, 1972, AM CERAM SOC BULL, V51, P336
[10]   VERIFICATION OF EXISTENCE OF CUBIC ZIRCONIA AT HIGH TEMPERATURE [J].
SMITH, DK ;
CLINE, CF .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1962, 45 (05) :249-250