Synthesis of Orthorhombic Mo-V-Sb Oxide Species by Assembly of Pentagonal Mo6O21 Polyoxometalate Building Blocks

被引：83

作者：

Sadakane, Masahiro ^{[1
]}

Yamagata, Keiko ^{[1
]}

Kodato, Katsunori ^{[1
]}

Endo, Keisuke ^{[1
]}

Toriumi, Koshiro ^{[2
]}

Ozawa, Yoshiki ^{[2
]}

Ozeki, Tomoji ^{[3
]}

Nagai, Takuro ^{[4
]}

Matsui, Yoshio ^{[4
]}

Sakaguchi, Norihito ^{[5
]}

Pyrz, William D. ^{[6
]}

Buttrey, Douglas J. ^{[6
]}

Blom, Douglas A. ^{[7
,8
]}

Vogt, Thomas ^{[7
,8
]}

Ueda, Wataru ^{[1
]}

机构：

[1] Hokkaido Univ, Catalysis Res Ctr, Sapporo, Hokkaido 0010021, Japan

[2] Hyogo Med Univ, Grad Sch Mat Sci, Kamigori, Hyogo 6781297, Japan

[3] Tokyo Inst Technol, Dept Chem & Mat Sci, Meguro Ku, Tokyo 1528551, Japan

[4] Natl Inst Mat Sci, Adv Nano Characterizat Ctr, Adv Elect Microscopy Grp, Tsukuba, Ibaraki 3050044, Japan

[5] Hokkaido Univ, Ctr Adv Res Energy Convers Mat, High Voltage Elect Microscope Lab, Sapporo, Hokkaido 0608626, Japan

[6] Univ Delaware, Ctr Catalyt Sci & Technol, Newark, DE 19716 USA

[7] Univ S Carolina, Dept Chem & Biocheem, Columbia, SC 29208 USA

[8] Univ S Carolina, NanoCtr & Elect Microscopy Ctr, NanoCtr, Columbia, SC 29208 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 21期

关键词：

molybdenum; oxides; pentagonal building blocks; polyoxometalates; X-RAY-DIFFRACTION; M1; PHASE; CATALYSTS; SPHERES; AMMOXIDATION; ZEOLITES; CLUSTERS; INSIGHTS; PROPANE; GROWTH;

D O I：

10.1002/anie.200805792

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Mix and match: The pentagonal [Mo6O21] n-polyoxomolybdate building block assembles with other sources of Mo, V, and Sb ions to form an orthorhombic Mo-V-Sb oxide. The first single-crystal X-ray analysis of an orthorhombic Mo-V-based oxide, a promising catalyst for light alkane selective oxidation known as the "M1 phase", revealed the structure of the compound. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：3782 / 3786

页数：5

共 46 条

[11] Triangular geometrical and magnetic motifs uniquely linked on a spherical capsule surface [J].

Müller, A ;

Todea, AM ;

van Slageren, J ;

Dressel, M ;

Bögge, H ;

Schmidtmann, M ;

Luban, M ;

Engelhardt, L ;

Rusu, M .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (25) :3857-3861

[12] Multifunctional metal oxide based nanoobjects:: spherical porous capsules/artificial cells and wheel-shaped species with unprecedented materials properties [J].

Müller, A ;

Roy, S .

JOURNAL OF MATERIALS CHEMISTRY, 2005, 15 (44) :4673-4677

[13] Linking giant molybdenum oxide based nano-objects based on well defined surfaces in different phases [J].

Müller, A ;

Roy, S .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2005, (18) :3561-3570

[14]

Müller A, 1999, ANGEW CHEM INT EDIT, V38, P3238

[15]

Müller A, 1999, ANGEW CHEM INT EDIT, V38, P3241, DOI 10.1002/(SICI)1521-3773(19991102)38:21<3241::AID-ANIE3241>3.0.CO

[16]

2-9

[17] Giant metal-oxide-based spheres and their topology:: from pentagonal building blocks to keplerates and unusual spin systems [J].

Müller, A ;

Kögerler, P ;

Dress, AWM .

COORDINATION CHEMISTRY REVIEWS, 2001, 222 :193-218

[18] Polyoxometalates: Very large clusters - Nanoscale magnets [J].

Muller, A ;

Peters, F ;

Pope, MT ;

Gatteschi, D .

CHEMICAL REVIEWS, 1998, 98 (01) :239-271

[19]

Müller A, 1998, ANGEW CHEM INT EDIT, V37, P3360, DOI 10.1002/(SICI)1521-3773(19981231)37:24<3359::AID-ANIE3359>3.0.CO

[20]

2-J

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