Synthesis of Orthorhombic Mo-V-Sb Oxide Species by Assembly of Pentagonal Mo6O21 Polyoxometalate Building Blocks

被引：83

作者：

Sadakane, Masahiro ^{[1
]}

Yamagata, Keiko ^{[1
]}

Kodato, Katsunori ^{[1
]}

Endo, Keisuke ^{[1
]}

Toriumi, Koshiro ^{[2
]}

Ozawa, Yoshiki ^{[2
]}

Ozeki, Tomoji ^{[3
]}

Nagai, Takuro ^{[4
]}

Matsui, Yoshio ^{[4
]}

Sakaguchi, Norihito ^{[5
]}

Pyrz, William D. ^{[6
]}

Buttrey, Douglas J. ^{[6
]}

Blom, Douglas A. ^{[7
,8
]}

Vogt, Thomas ^{[7
,8
]}

Ueda, Wataru ^{[1
]}

机构：

[1] Hokkaido Univ, Catalysis Res Ctr, Sapporo, Hokkaido 0010021, Japan

[2] Hyogo Med Univ, Grad Sch Mat Sci, Kamigori, Hyogo 6781297, Japan

[3] Tokyo Inst Technol, Dept Chem & Mat Sci, Meguro Ku, Tokyo 1528551, Japan

[4] Natl Inst Mat Sci, Adv Nano Characterizat Ctr, Adv Elect Microscopy Grp, Tsukuba, Ibaraki 3050044, Japan

[5] Hokkaido Univ, Ctr Adv Res Energy Convers Mat, High Voltage Elect Microscope Lab, Sapporo, Hokkaido 0608626, Japan

[6] Univ Delaware, Ctr Catalyt Sci & Technol, Newark, DE 19716 USA

[7] Univ S Carolina, Dept Chem & Biocheem, Columbia, SC 29208 USA

[8] Univ S Carolina, NanoCtr & Elect Microscopy Ctr, NanoCtr, Columbia, SC 29208 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 21期

关键词：

molybdenum; oxides; pentagonal building blocks; polyoxometalates; X-RAY-DIFFRACTION; M1; PHASE; CATALYSTS; SPHERES; AMMOXIDATION; ZEOLITES; CLUSTERS; INSIGHTS; PROPANE; GROWTH;

D O I：

10.1002/anie.200805792

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Mix and match: The pentagonal [Mo6O21] n-polyoxomolybdate building block assembles with other sources of Mo, V, and Sb ions to form an orthorhombic Mo-V-Sb oxide. The first single-crystal X-ray analysis of an orthorhombic Mo-V-based oxide, a promising catalyst for light alkane selective oxidation known as the "M1 phase", revealed the structure of the compound. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：3782 / 3786

页数：5

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