Efficient near-infrared emission in Eu3+-Yb3+-Y3+ tri-doped cubic ZrO2 via down-conversion for silicon solar cells

被引:15
作者
Liao, Jinsheng [1 ]
Zhou, Dan [1 ]
Liu, Shaohua [1 ]
Wen, He-Rui [1 ]
Qiu, Xin [1 ]
Chen, Jinglin [1 ]
机构
[1] Jiangxi Univ Sci & Technol, Sch Met & hem Engn, Ganzhou 341000, Jiangxi, Peoples R China
基金
中国国家自然科学基金;
关键词
Optical materials; Quantum cutting; Near infrared; Energy transfer; SPECTROSCOPIC PROPERTIES; ENERGY; PHOTOLUMINESCENCE; YB3+; EU3+; DOWNCONVERSION; PERFORMANCE;
D O I
10.1016/j.physb.2013.10.043
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
Eu3+-Yb3+-Y3+ tri-doped cubic ZrO2 (abbreviated as YSZ:Eu,Yb) phosphors with different doping concentrations of Yb3+ can be synthesized via the Pechini sol-gel method. Efficient near-infrared (NlR) emission in YSZ:Eu,Yb phosphors was demonstrated. The dependence of the intensities of visible and NlR emissions, decay lifetimes and energy-transfer efficiencies on the Yb3+ doping concentration was investigated in detail, It is found that Eu3+, acting as a sensitizer, can efficiently transfer its energy to Yb3+ activator ions in YSZ:Eu,Yb phosphors. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:59 / 63
页数:5
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