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Synthesis and Characterization of Boron Incorporated Polyester Polyol from Linseed Oil: A Sustainable Material
被引:15
作者:
Akram, Deewan
[1
]
Sharmin, Eram
[1
]
Ahmad, Sharif
[1
]
机构:
[1] Jamia Millia Islamia, Dept Chem, Mat Res Lab, New Delhi 110025, India
关键词:
differential scanning calorimetry;
NMR;
polyesters;
resins;
synthesis;
SEED OIL;
POLYMERS;
D O I:
10.1002/masy.200950316
中图分类号:
O63 [高分子化学(高聚物)];
学科分类号:
070305 ;
080501 ;
081704 ;
摘要:
Polyols obtained from seed oils have established themselves as excellent building blocks of polymers, viz. polyurethanes. In this work, a novel attempt has been made to incorporate boron in the backbone of polyol [LPO] derived from linseed oil. Furthermore, LPO was treated with phthalic anhydride [PA] and boric acid [BA] (in different molar ratios) to obtain boron incorporated linseed polyester polyols [BPPEs] through solvent less synthesis process. BPPEs were characterized by spectroscopic techniques (IR,H-1 NMR and C-13 NMR) to confirm the incorporation of boron and also to elucidate their structures. Physico-chemical characterization and antibacterial behavior of BPPEs was also investigated. it is speculated that these resins may serve as excellent raw materials for adhesives, coatings and as antibacterial agents.
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页码:130 / 137
页数:8
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