Synthesis and Characterization of Boron Incorporated Polyester Polyol from Linseed Oil: A Sustainable Material

被引:15
作者
Akram, Deewan [1 ]
Sharmin, Eram [1 ]
Ahmad, Sharif [1 ]
机构
[1] Jamia Millia Islamia, Dept Chem, Mat Res Lab, New Delhi 110025, India
关键词
differential scanning calorimetry; NMR; polyesters; resins; synthesis; SEED OIL; POLYMERS;
D O I
10.1002/masy.200950316
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Polyols obtained from seed oils have established themselves as excellent building blocks of polymers, viz. polyurethanes. In this work, a novel attempt has been made to incorporate boron in the backbone of polyol [LPO] derived from linseed oil. Furthermore, LPO was treated with phthalic anhydride [PA] and boric acid [BA] (in different molar ratios) to obtain boron incorporated linseed polyester polyols [BPPEs] through solvent less synthesis process. BPPEs were characterized by spectroscopic techniques (IR,H-1 NMR and C-13 NMR) to confirm the incorporation of boron and also to elucidate their structures. Physico-chemical characterization and antibacterial behavior of BPPEs was also investigated. it is speculated that these resins may serve as excellent raw materials for adhesives, coatings and as antibacterial agents.
引用
收藏
页码:130 / 137
页数:8
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