Synthesis and Characterization of Boron Incorporated Polyester Polyol from Linseed Oil: A Sustainable Material

被引:15
作者
Akram, Deewan [1 ]
Sharmin, Eram [1 ]
Ahmad, Sharif [1 ]
机构
[1] Jamia Millia Islamia, Dept Chem, Mat Res Lab, New Delhi 110025, India
关键词
differential scanning calorimetry; NMR; polyesters; resins; synthesis; SEED OIL; POLYMERS;
D O I
10.1002/masy.200950316
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Polyols obtained from seed oils have established themselves as excellent building blocks of polymers, viz. polyurethanes. In this work, a novel attempt has been made to incorporate boron in the backbone of polyol [LPO] derived from linseed oil. Furthermore, LPO was treated with phthalic anhydride [PA] and boric acid [BA] (in different molar ratios) to obtain boron incorporated linseed polyester polyols [BPPEs] through solvent less synthesis process. BPPEs were characterized by spectroscopic techniques (IR,H-1 NMR and C-13 NMR) to confirm the incorporation of boron and also to elucidate their structures. Physico-chemical characterization and antibacterial behavior of BPPEs was also investigated. it is speculated that these resins may serve as excellent raw materials for adhesives, coatings and as antibacterial agents.
引用
收藏
页码:130 / 137
页数:8
相关论文
共 50 条
[21]   Spectroscopic characterization and microbial degradation of engineered bio-elastomers from linseed oil [J].
Das, Rakesh ;
Pramanik, Nilkamal ;
Kundu, Patit P. .
JOURNAL OF POLYMER ENGINEERING, 2015, 35 (03) :287-301
[22]   Comparative Thermo-Mechanical Properties of Sustainable Epoxy Polymer Networks Derived from Linseed Oil [J].
Necolau, Madalina Ioana ;
Damian, Celina Maria ;
Olaret, Elena ;
Iovu, Horia ;
Balanuca, Brindusa .
POLYMERS, 2022, 14 (19)
[23]   Development of Anticorrosive Poly(Ether-Urethane) Amide Coatings from Linseed Oil: A Sustainable Resource [J].
Alam, Manawwer ;
Ashraf, S. M. ;
Ray, Alok R. ;
Ahmad, Sharif .
JOURNAL OF POLYMERS AND THE ENVIRONMENT, 2010, 18 (03) :208-215
[24]   SYNTHESIS OF UNSATURATED POLYESTER FROM GLYCOLYZED PET WASTE AND CHARACTERIZATION [J].
Katoch, Slinain ;
Sharma, Vinay ;
Kumar, Vinay ;
Kundu, Patit P. .
JOURNAL OF POLYMER ENGINEERING, 2009, 29 (04) :199-211
[25]   Preparation and characterization of a bio-based polymeric wood adhesive derived from linseed oil [J].
Addis, Clark C. ;
Koh, Rachel S. ;
Gordon, Melissa B. .
INTERNATIONAL JOURNAL OF ADHESION AND ADHESIVES, 2020, 102
[26]   Morphological and Thermal Characterization of Linseed-Oil Based Polymers from Cationic and Thermal Polymerization [J].
Sharma, Vinay ;
Banait, J. S. ;
Larock, R. C. ;
Kundu, P. P. .
JOURNAL OF POLYMERS AND THE ENVIRONMENT, 2010, 18 (03) :235-242
[27]   Synthesis and Characterization of Chelating Hyperbranched Polyester Nanoparticles for Cd(II) Ion Removal from Water [J].
Alregeb, Faten ;
Khalili, Fawwaz ;
Sweileh, Bassam ;
Ali, Dalia Khalil .
MOLECULES, 2022, 27 (12)
[28]   Synthesis and Spectroscopic Characterization of Vanadium-Incorporated V-AIMCM-48 Mesoporous Material [J].
Back, Gernho ;
Yu, Jong-Sung ;
Park, Sung-Kun ;
Lee, Chul Wee ;
Won, Taejin .
KOREAN CHEMICAL ENGINEERING RESEARCH, 2006, 44 (04) :369-374
[29]   Synthesis and characterization of waste polyethylene reinforced modified castor oil-based polyester biocomposite [J].
Aydogmus, Ercan ;
Dag, Mustafa ;
Yalcin, Zehra Gulten ;
Arslanoglu, Hasan .
JOURNAL OF APPLIED POLYMER SCIENCE, 2022, 139 (27)
[30]   Synthesis and Characterization of Unsaturated Biobased-Polyamides from Plant Oil [J].
Ahmadi, Reza ;
Ullah, Aman .
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2020, 8 (21) :8049-8058