New thermodynamic potentials for surface science

被引：8

作者：

Rusanov, Anatoly I. ^{[1
]}

机构：

[1] St Petersburg State Univ, Mendeleev Ctr, St Petersburg 199034, Russia

来源：

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS | 2014年 / 443卷

关键词：

J-potential; Fundamental equations; Surface tension; Line tension; Neumann equation; SOLID-SURFACES;

D O I：

10.1016/j.colsurfa.2013.11.036

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

J-potential belongs to the group of novel thermodynamic potentials for arbitrarily loaded solids. The article considers two modified forms of J-potential especially convenient for surface science. Definitions are given and fundamental equations are derived for bulk phases, interfaces, and interfacial lines. The application of J-potential is illustrated by deriving the Neumann and Gibbs equations for a number of interfaces meeting at a line, and the classical Young equation. (C) 2013 Elsevier B.V. All rights reserved.

引用

页码：363 / 367

页数：5

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