Efficient and Z-selective cross-metathesis of conjugated enynes

被引：75
|
作者：
Hansen, EC [1 ]
Lee, D [1 ]
机构：
[1] Univ Wisconsin, Dept Chem, Madison, WI 53706 USA
来源：
ORGANIC LETTERS | 2004年 / 6卷 / 12期
关键词：
D O I：
10.1021/ol049378i
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The generation of a conjugated alkynyl alkylidene has been achieved using an allyl ether moiety as an intramolecular catalyst delivery vehicle. The reaction of this intermediate with alkenes and alkynes yields conjugated enynes with Z-selectivity.
引用
收藏
页码：2035 / 2038
页数：4
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