Self-assembly formation of mechanically interlocked [2]- and [3] catenanes using lanthanide ion [Eu(III)] templation and ring closing metathesis reactions

被引:80
作者
Lincheneau, Christophe
Jean-Denis, Bernard
Gunnlaugsson, Thorfinnur [1 ]
机构
[1] Univ Dublin Trinity Coll, Sch Chem, Dublin 2, Ireland
基金
爱尔兰科学基金会;
关键词
METAL-DIRECTED SYNTHESIS; COORDINATION BUNDLES; MOLECULAR SHUTTLES; ROTAXANES; COMPLEXES; LIGAND; KNOTS; SENSORS; DESIGN; WATER;
D O I
10.1039/c3cc49640f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The formation of interlocked lanthanide-based catenanes using Eu(III)-directed synthesis is described (catenation being achieved via a ring-closing metathesis reaction); the self-assembly formation of the supramolecular structures was analysed by HRMS, NMR and luminescent spectroscopies.
引用
收藏
页码:2857 / 2860
页数:4
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