Femtosecond studies of solvation and intramolecular configurational dynamics of fluorophores in liquid solution

被引:261
作者
Glasbeek, M [1 ]
Zhang, H [1 ]
机构
[1] Univ Amsterdam, Phys Chem Lab, NL-1018 WS Amsterdam, Netherlands
关键词
D O I
10.1021/cr0206723
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A comprehensive review of ultrafast studies of large-sized fluorophores in liquid solution performed in the past decade using the femtosecond fluorescence up-conversion technique is presented. Femtosecond transient absorption results relevant for better understanding of the up-conversion results of some of the chromophores are included. It is hoped that the review gives a perspective of how femtosecond fluorescence up-conversion experiments can be utilized to disentangle the contributions of intramolecular interactions on one hand and solvation dynamics on the other hand in excited-state relaxation of large molecules with great potential for applications in different fields.
引用
收藏
页码:1929 / 1954
页数:26
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