Metal free oxidative coupling of aryl formamides with alcohols for the synthesis of carbamates

被引：20
作者：
Reddy, N. Veera [1 ]
Prasad, K. Rajendra [1 ]
Reddy, P. Sudhir [1 ]
Kantam, M. Lakshmi [1 ]
Reddy, K. Rajender [1 ]
机构：
[1] CSIR Indian Inst Chem Technol, Inorgan & Phys Chem Div, Hyderabad 500607, Andhra Pradesh, India
来源：
ORGANIC & BIOMOLECULAR CHEMISTRY | 2014年 / 12卷 / 14期
关键词：
H BOND ACTIVATION; HOFMANN REARRANGEMENT; DIRECT AMIDATION; AMINES; FUNCTIONALIZATION; EFFICIENT; CARBONYLATION; COPOLYMERS; HALIDES; ACCESS;
D O I：
10.1039/c4ob00066h
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A direct transformation of N-aryl formamides to the corresponding carbamates via the formation of isocyanate intermediates is achieved in good yields using hypervalent iodine as an oxidant.
引用
收藏
页码：2172 / 2175
页数：4
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