Metal free oxidative coupling of aryl formamides with alcohols for the synthesis of carbamates

被引：20

作者：

Reddy, N. Veera ^{[1
]}

Prasad, K. Rajendra ^{[1
]}

Reddy, P. Sudhir ^{[1
]}

Kantam, M. Lakshmi ^{[1
]}

Reddy, K. Rajender ^{[1
]}

机构：

[1] CSIR Indian Inst Chem Technol, Inorgan & Phys Chem Div, Hyderabad 500607, Andhra Pradesh, India

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2014年 / 12卷 / 14期

关键词：

H BOND ACTIVATION; HOFMANN REARRANGEMENT; DIRECT AMIDATION; AMINES; FUNCTIONALIZATION; EFFICIENT; CARBONYLATION; COPOLYMERS; HALIDES; ACCESS;

D O I：

10.1039/c4ob00066h

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A direct transformation of N-aryl formamides to the corresponding carbamates via the formation of isocyanate intermediates is achieved in good yields using hypervalent iodine as an oxidant.

引用

页码：2172 / 2175

页数：4

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