Phase diagrams and rheological properties of cellulose ether solutions in magnetic field

被引:17
作者
Vshivkov, S. A. [1 ]
Rusinova, E. V. [1 ]
Galyas, A. G. [1 ]
机构
[1] Ural Fed Univ, Dept Chem, Ekaterinburg 620002, Russia
基金
俄罗斯基础研究基金会;
关键词
Phase diagram; Rheology; Magnetic field; Liquid crystal; Cellulose ethers; LIQUID-CRYSTALLINE SOLUTIONS; BENZYL-L-GLUTAMATE; NON-NEWTONIAN VISCOSITY; HYDROXYPROPYL CELLULOSE; CONCENTRATED-SOLUTIONS; AQUEOUS-SOLUTIONS; WATER SYSTEM; TRANSITIONS; POLYPEPTIDE; MACROMOLECULES;
D O I
10.1016/j.eurpolymj.2014.07.042
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The phase transitions and rheological properties of the hydroxyethyl cellulose-water, hydroxyethyl cellulose-DMAA, hydroxyethyl cellulose-DMF, hydroxypropyl cellulose-water, hydroxypropyl cellulose-DMF and ethyl cellulose-DMAA systems were studied. The regions of existence of the isotropic and anisotropic phases were determined. Application of a magnetic field is shown to be accompanied by a change in the relative viscosity by a factor of 1.3-4. The concentration dependences of viscosity in the presence of a magnetic field are described by curves with an extremum. (C) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码:326 / 332
页数:7
相关论文
共 50 条
  • [21] Liquid crystal phase transitions and rheological properties of cellulose ethers
    S. A. Vshivkov
    E. V. Rusinova
    Russian Journal of Applied Chemistry, 2011, 84 : 1830 - 1835
  • [22] The role of oil concentration on the rheological properties, microstructure, and in vitro digestion of cellulose ether emulsions
    Martinez, S.
    Espert, M.
    Salvador, A.
    Sanz, T.
    FOOD HYDROCOLLOIDS, 2022, 131
  • [23] Phase diagrams and magnetic properties of a cylindrical Ising nanowire: Monte Carlo and effective field treatments
    Boughrara, M.
    Kerouad, M.
    Zaim, A.
    JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2014, 368 : 169 - 179
  • [24] Effect of Magnetic Field on Phase Transitions and Structure of Polyelectrolyte Solutions
    Vshivkov, S. A.
    Rusinova, E. V.
    Klyuzhin, E. S.
    Kapitanov, A. A.
    POLYMER SCIENCE SERIES A, 2020, 62 (01) : 62 - 69
  • [25] Changes in Rheological Properties of Mortars with Steel Slags and Steel Fibers by Magnetic Field
    Kang, Dukman
    Moon, Doyoung
    Kim, Wooseok
    MATERIALS, 2021, 14 (14)
  • [26] Calculated phase diagrams for cellulose/ammonia/ammonium thiocyanate solutions in comparison to experimental results
    Margaret W. Frey
    Michael H. Theil
    Cellulose, 2004, 11 : 53 - 63
  • [27] Calculated phase diagrams for cellulose/ammonia/ammonium thiocyanate solutions in comparison to experimental results
    Frey, MW
    Theil, MH
    CELLULOSE, 2004, 11 (01) : 53 - 63
  • [28] Rheological properties of aqueous H-carboxymethyl cellulose solutions with various additives
    Bochek, AM
    Yusupova, LD
    Zabivalova, NM
    Petropavlovskii, GA
    RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 2002, 75 (04) : 645 - 648
  • [29] Rheological Properties of Cellulose/Ionic Liquid Solutions: From Dilute to Concentrated States
    Gericke, Martin
    Schlufter, Kerstin
    Liebert, Tim
    Heinze, Thomas
    Budtova, Tatiana
    BIOMACROMOLECULES, 2009, 10 (05) : 1188 - 1194
  • [30] Effect of Magnetic Field on Phase Transitions in Solutions and Melts of Flexible Polymers
    Vshivkov, S. A.
    Zhernov, I. V.
    Nadol'skii, A. L.
    Mizyov, A. S.
    POLYMER SCIENCE SERIES A, 2017, 59 (04) : 465 - 472